摘要 以钒钛磁铁矿炼铁原料为基础,系统研究了烧结矿中MgO质量分数对高炉冶炼钒钛磁铁矿综合炉料软熔滴落性能和V,Cr在渣铁中迁移规律的影响,并进行了理论分析.研究表明,随着烧结矿中MgO质量分数的提高,综合炉料的软化区间t○40-t○4变宽;熔化区间t○D-t○S稍有收窄,软熔带变薄且位置略微下移;熔滴性能总特征值S先减小后增大,综合炉料透气性先变好后恶化,在MgO质量分数为2.98%~3.40%时透气性最好;滴落率逐渐变小;V, Cr在滴落铁中的收得率略有降低;因此,烧结矿中MgO质量分数在3.40%左右为宜,此时高炉渣中MgO质量分数约为12%.Abstract:Effects of MgO content in sinter on softening-dripping behavior of vanadium-titanium magnetite composite burden and the migration patterns of V, Cr in slag-iron were studied. The results showed that with the increasing of MgO in sinter, the softening range t40-t4 tends to be wider,the melting range tD-tS is narrowed slightly. The cohesive zone tends to be narrow and its location is shifted down but not obvious. Softening-dripping characteristics S decreases at first then increases, the permeability tends to be better then worse, when the content of MgO is between 2.98% and 3.40%, the permeability is the best. The dripping ratio tends to be declining; when MgO is increased, it is not conducive to the reduction of V, Cr. The optimal content of MgO in the sinter is around 3.40% and the content of MgO in BF slag is about 12%.
References
[1]
朱俊士.钒钛磁铁矿选矿及综合利用[J].金属矿山,2000,283(1):1-5.(Zhu Jun-shi.Ore dressing and comprehensive utilization of vanadium-titanium magnetite[J].Metal Mine,2000,283(1):1-5.)
[2]
杜鹤桂.高炉冶炼钒钛磁铁矿原理[M].北京:科学出版社,1996:1-16.(Du He-gui.Smelting principle of vanadium-titanium magnetite in blast furnace[M].Beijing:Science Press,1996:1-16.)
[3]
Jena B C,Dredler W,Reilly I G.Extraction of titanium,vanadium and iron from titanmagnetite deposits at pipestone lake,Manitoba,Canada [J].Minerals Engineering,1998,8(1/2):159-168.
[4]
姜鑫,吴钢生,金明芳,等.MgO对烧结矿软熔性能的影响[J].东北大学学报:自然科学版,2006,27(12):1358-1360.(Jiang Xin,Wu Gang-sheng,Jin Ming-fang,et al.Effects of MgO on sinter softening-dripping behavior[J].Journal of Northeastern University:Natural Science,2006,27(12):1358-1360.)
[5]
姜鑫,吴钢生,魏国,等.MgO对烧结工艺及烧结矿冶金性能的影响[J].钢铁,2006,41(3):9-11.(Jiang Xin,Wu Gang-sheng,Wei Guo,et al.Effects of MgO on the sintering process and the sinter metallurgical properties [J].Iron and Steel,2006,41(3):9-11.)
Yadav U S,Pandey B D.Influence of magnesia on sintering characteristics of iron ore [J].Ironmaking and Steelmaking,2002,29(2):91-94.
[8]
Gunther S.Experiment and study on effects of different basicity and contents of MgO and SiO2 in sinter [J].ISIJ International,1998,38(7):457-462.
[9]
储满生.钢铁冶金原燃料及辅助材料[M].北京:冶金工业出版社,2010.(Chu Man-sheng.Fuel and auxiliary materials of iron and steel metallurgy[M].Beijing:Metallurgical Industry Press,2010.)
[10]
Tocarovskii I G,Bolshakov V I,Togobitskaya D N,et al.Influence of the softening and melting zone on blast-furnace smelting[J].Steel in Translation,2009,39 (1):34-44.