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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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甲酸为氢源的甘油催化选择氢解
DOI: 10.1016/S1872-2067(12)60656-1, PP. 2066-2074
Keywords: 铜,二氧化锆,氢解,甘油,甲酸
Abstract:
？以甲酸作为氢源,采用铜基复合金属氧化物催化剂,催化氢解甘油制备1,2-丙二醇,其中液相甲酸的高选择性分解是实现甘油氢解的必要和关键步骤.活性测试表明,高分散的铜和ZrO2载体间的协同作用对甲酸分解和甘油到1,2-丙二醇的转化至关重要,20%Cu/ZrO2催化剂的活性最佳.由于避免使用相对昂贵的化石燃料氢,因而该催化体系在生物质的高值利用方面具有潜在的应用前景.
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