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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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基于C-H键活化的铜催化二苄胺氧化酰胺化反应
DOI: 10.1016/S1872-2067(12)60617-2, PP. 1644-1650
Keywords: C-H键活化,铜催化剂,二乙酸碘苯,氧化酰基化,二苄胺
Abstract:
？基于铜催化的C-H键活化构建了一类高效的二苄胺氧化酰基化生成N-苄基苯甲酰胺的反应.该反应使用CuBr作为催化剂,二乙酸碘苯作为氧化剂,在温和条件下生成两种酰胺,总产率最高可达92.0%.CuBr催化剂价廉易得,催化活性高.同时这也是首次使用二乙酸碘苯作为氧化剂,通过二苄胺的直接氧化酰基化反应合成N-苄基苯甲酰胺.
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