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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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负载型铜基催化剂组分间相互作用及其催化性能
DOI: 10.1016/S1872-2067(12)60592-0, PP. 851-864
Keywords: 负载型铜基催化剂,表面相互作用,嵌入模型,一氧化碳完全氧化,CO+NO反应,NH3+NO+O2反应
Abstract:
？负载型铜基催化剂因其良好的催化性能和相对低廉的价格在诸多重要工业催化反应中得到广泛的应用.探讨负载型铜基催化剂中组分间的相互作用,有助于了解相关催化作用的本质,为现有催化剂的改进和新催化剂的设计提供科学依据.本文综述了近年来我们就CuO在不同载体上的分散、铜物种和载体的改性及其物理化学性质以及催化CO完全氧化、CO+NO和NH3+NO+O2反应性能等方面的研究进展.结果表明,CuO在多种氧化物载体表面的分散和所得负载型铜基催化剂的一些物理化学性质可参考“嵌入模型”得到解释,本文主要讨论了以CeO2,CexZr1-xO2和Mo3-CeO2为载体的一些铜基催化剂的组成-结构-性质间的关系.
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