|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
NO在Cu(111)表面吸附和分解的XPS和TPD研究：不同氧物种的影响
DOI: 10.1016/S1872-2067(12)60585-3, PP. 964-972
Keywords: 一氧化氮,Cu(111)表面,氧物种,吸附,X射线光电子能谱,程序升温脱附谱
Abstract:
？利用X射线光电子能谱和程序升温脱附谱研究了NO在清洁和预吸附氧的Cu(111)表面上的吸附和反应.通过改变NO的暴露量和退火温度,在Cu(111)表面可以制备出不同种类的化学吸附氧物种,其O1s的结合能分别位于531.0eV(O531)和529.7eV(O529).表面O531物种的存在对NO的不同吸附状态有着显著影响,同时使得大部分NO吸附分子(NO(a))在加热过程中发生分解并以N2O和N2形式脱附;而表面O529物种对NO(a)的解离脱附有着明显的抑制作用.相对于O531物种来说,O529物种对NO吸附表现出更强的位阻效应.上述结果表明,NO在Cu(111)表面的吸附和分解行为与预吸附氧物种的种类和覆盖度密切相关.
| [1] | Szanyi J, Goodman D W. Catal Lett, 1993, 21: 165
|
| [2] | Millar G J, Canning A, Rose G, Wood B, Trewartha L, Mackinnon I D R. J Catal, 1999, 183: 169
|
| [3] | Yang Y X, Evans J, Rodriguez J A, White M G, Liu P. Phys Chem Chem Phys, 2010, 12: 9909
|
| [4] | Yang F, Choi Y M, Agnoli S, Liu P, Stacchiola D, Hrbek J, Rodriguez J A. J Phys Chem C, 2011, 115: 23062
|
| [5] | Gao Z M, Zhou M, Deng H, Yue Y. J Nat Gas Chem, 2012, 21: 513
|
| [6] | Cao J L, Wang Y, Ma T Y, Liu Y P, Yuan Z Y. J Nat Gas Chem, 2011, 20: 669
|
| [7] | Salmeron M, Schl？gl R. Surf Sci Rep, 2008, 63: 169
|
| [8] | Johnson D W, Matloob M H, Roberts M W. J Chem Soc, Chem Comm, 1978: 40
|
| [9] | Johnson D W, Matloob M H, Roberts M W. J Chem Soc, Faraday Trans, 1979, 75: 2143
|
| [10] | Wendelken J F. J Vac Sci Technol, 1982, 20: 884
|
| [11] | Balkenende A R, Gijzeman O L J, Geus J W. Appl Surf Sci, 1989, 37: 189
|
| [12] | Balkenende A R, den Daas H, Huisman M, Gijzeman O L J, Geus J W. Appl Surf Sci, 1991, 47: 341
|
| [13] | So S K, Franchy R, Ho W. J Chem Phys, 1991, 95: 1385
|
| [14] | Balkenende A R, Hoogendam R, de Beer T, Gijzeman O L J, Geus J W. Appl Surf Sci, 1992, 55: 1
|
| [15] | Fernández-García M, Conesa J C, Illas F. Surf Sci, 1993, 280: 441
|
| [16] | Wee A T S, Lin J, Huan A C H, Loh F C, Tan K L. Surf Sci, 1994, 304: 145
|
| [17] | Brown W A, Sharma R K, King D A, Haq S. J Phys Chem, 1996, 100: 12559
|
| [18] | Illas F, Ricart J M, Fernandez-Garcia M. J Chem Phys, 1996, 104: 5647
|
| [19] | Sueyoshi T, Sasaki T, Iwasawa Y. J Phys Chem, 1996, 100: 13646
|
| [20] | van Daelen M A, Li Y S, Newsam J M, van Santen R A. J Phys Chem, 1996, 100: 2279
|
| [21] | Dumas P, Suhren M, Chabal Y J, Hirschmugl C J, Williams G P. Surf Sci, 1997, 371: 200
|
| [22] | Carley A F, Davies P R, Harikumar K R, Jones R V, Kulkarni G U, Roberts M W. Top Catal, 2000, 14: 101
|
| [23] | Carley A F, Davies P R, Harikumar K R, Jones R V, Kulkarni G U, Roberts M W. Top Catal, 2001, 14: 101
|
| [24] | Bogicevic A, Hass K C. Surf Sci, 2002, 506: L237
|
| [25] | Kim C M, Yi C W, Goodman D W. J Phys Chem B, 2002, 106: 7065
|
| [26] | Yen M-Y, Ho J-J. Chem Phys, 2010, 373: 300
|
| [27] | Matloob M H, Roberts M W. J Chem Soc, Faraday Trans, 1977, 73: 1393
|
| [28] | Davies P R, Roberts M W, Shukla N, Vincent D J. Surf Sci, 1995, 325: 50
|
| [29] | Davies P R, Shukla N, Vincent D J. J Chem Soc, Faraday Trans, 1995, 91: 2885
|
| [30] | Behm R J, Brundle C R. J Vac Sci Technol, A, 1984, 2: 1040
|
| [31] | Zhu J F, Kinne M, Fuhrmann T, Denecke R, Steinrück H P. Surf Sci, 2003, 529: 384
|
| [32] | Skelly J F, Bertrams T, Munz A W, Murphy M J, Hodgson A. Surf Sci, 1998, 415: 48
|
| [33] | Kirstein W, Krüger B, Thieme F. Surf Sci, 1986, 176: 505
|
| [34] | Bloch J, Bottomley D J, Janz S, van Driel H M, Timsit R S. J Chem Phys, 1993, 98: 9167
|
| [35] | Sueyoshi T, Sasaki T, Iwasawa Y. Surf Sci, 1996, 365: 310
|
| [36] | Wiame F, Maurice V, Marcus P. Surf Sci, 2007, 601: 1193
|
| [37] | Dubois L H. Surf Sci, 1982, 119: 399
|
| [38] | Moritani K, Okada M, Sato S, Goto S, Kasai T, Yoshigoe A, Teraoka Y. J Vac Sci Technol A, 2004, 22: 1625
|
| [39] | Moritani K, Okada M, Teraoka Y, Yoshigoe A, Kasai T. J Phys Chem C, 2008, 112: 8662
|
| [40] | Jiang Z Q, Huang W X, Tan D L, Zhai R S, Bao X H. Surf Sci, 2006, 600: 4860
|
| [41] | Zhu J F, Kinne M, Fuhrmann T, Trankenschuh B, Denecke R, Steinruck H P. Surf Sci, 2003, 547: 410
|
| [42] | Root T W, Fisher G B, Schmidt L D. J Chem Phys, 1986, 85: 4687
|
| [43] | Chen J G, Erley W, Ibach H. Surf Sci, 1989, 224: 215
|
| [44] | Davies P R, Bowker M. Catal Today, 2010, 154: 31
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
