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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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Rh(III)催化的N-甲氧基苯甲酰胺系列物选择性C-H氰基化反应
DOI: 10.1016/S1872-2067(15)60872-5, PP. 1175-1182
Keywords: Rh(III)催化剂,C-H键氰基化,N-甲氧基苯甲酰胺系列物,N-氰基-N-苯基对甲苯磺酰胺,反应机制
Abstract:
？采用了最近热门的Rh(III)催化C-H键活化方法,以N-甲氧基苯甲酰胺系列物为反应底物,N-氰基-N-苯基对甲苯磺酰胺(NCTS)为氰基化试剂,高效合成了含氰基官能团产物.结果表明,该反应在碳酸银存在下,使用二氧六环作为反应溶剂,于80℃反应8h生成的邻位氰基取代的N-甲氧基苯甲酰胺的产率较高.进一步研究表明,该反应具有好的区域选择性和底物/官能团适应性.一系列机理实验研究表明,该反应可能采用了一个内部的亲电取代机制及使用了C-H键切割步骤作为关键限速步骤.考虑到该反应产物包含有价值的结构单元-N-甲氧基甲酰胺和氰基取代基,因而有望用于现代有机合成中.
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