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OALib Journal期刊
ISSN: 2333-9721
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纳米尺度NiLa2O4尖晶石催化NaBH4还原亚胺制仲胺
DOI: 10.1016/S1872-2067(15)60921-4, PP. 1191-1196
Keywords: 亚胺,还原,仲胺,硼氢化钠,纳米尺度尖晶石,镧酸镍
Abstract:
？由溶胶-凝胶法制得的Ni-La化合物经热分解制备了纳米尺度NiLa2O4尖晶石,在750℃焙烧后形成了结晶良好的尖晶石结构.采用差热分析、X射线衍射、透射电镜、扫描电镜和粒度分布分析等手段表征了该尖晶石的物理化学性质.结果表明,该纳米颗粒有规则的外形和确定的晶面,由平均粒径为40nm的规整半球晶粒组成.精修的晶胞参数a=3.861205？和c=12.6793？.在NaBH4选择还原亚胺制相应仲胺的反应中,该新型纳米NiLa2O4尖晶石可用作高效多相催化剂,得到了较高的产物产率.所有反应可在室温和相对较短的时间内完成.在优化的反应条件下,均可得到带有不同芳基的,包括带有吸电子和供电子基团的仲胺.该催化剂回收简便,重复使用4次,其催化活性未见明显下降.
| [1] | Singh B, Guru S K, Sharma R, Bharate S S, Khan I A, Bhushan S, Bharate S B, Vishwakarma R A. Bioorg Med Chem Lett, 2014, 24: 4865
|
| [2] | Logan R, Kong A C, Krise J P. J Pharm Sci, 2014, 103: 3287
|
| [3] | Zhang Y, Quan Z J, Gong H P, Da Y X, Zhang Z, Wang X C. Tetrahedron, 2015, 71: 2113
|
| [4] | Bujnowski K, Synoradzki L, Zevaco T A, Dinjus E, Augustynowicz-Kopec E, Napiorkowska A. Tetrahedron, 2015, 71: 158
|
| [5] | Alsryfy A H, Mosaa Z A, Alrazzak N. Res J Pharm Biol Chem Sci, 2015, 6: 798
|
| [6] | Camps P, Gomez E, Munoz-Torrero D, Font-Bardia M, Solans X. Tetrahedron, 2003, 59: 4143
|
| [7] | Barbry D, Champagne P. Synth Commun, 1995, 25: 3503
|
| [8] | Sepelak V, Becker K D. Mater Sci Eng A, 2004, A375-A377: 861
|
| [9] | Khosravi I, Yazdanbakhsh M, Goharshadi E K, Youssefi A. Mater Chem Phys, 2011, 130: 1156
|
| [10] | Yazdanbakhsh M, Khosravi I, Mashhoori M S, Rahimizadeh M, Shiri A, Bakavoli M. Mater Res Bull, 2012, 47: 413
|
| [11] | Yazdanbakhsh M, Khosravi I, Goharshadi E K, Youssefi A. J Hazard Mater, 2010, 184: 684
|
| [12] | de Lima S P, Vicentini V, Fierro J L G, Rangel M C. Catal Today, 2008, 133-135: 925
|
| [13] | Khosravi I, Yazdanbakhsh M, Eftekhar M, Haddadi Z. Mater Res Bull, 2013, 48: 2213
|
| [14] | Khosravi I, Eftekhar M, Bayraq S S. Synth React Inorg Met Org Nano-Metal Chem, 2014, 44: 227
|
| [15] | Savoia D, Trombini C, Umani-Ronchi A. J Org Chem, 1978, 43: 2907
|
| [16] | de Nie-Sarink M J, Pandit U K. Tetrahedron Lett, 1979, 20: 2449
|
| [17] | Kojima Y, Suzuki K, Fukumoto K, Sasaki M, Yamamoto T, Kawai Y, Hayashi H. Int J Hydrogen Energy, 2002, 27: 1029
|
| [18] | Carey F A, Sundberg R J. Advanced Organic Chemistry, Part A: Structure and Mechanisms. 5th ed. New York: Springer, 2007. 169
|
| [19] | Fernandes V R, Pinto A M F R, Rangel C M. Int J Hydrogen Energy, 2010, 35: 9862
|
| [20] | Cho B T, Kang S K. Tetrahedron, 2005, 61: 5725
|
| [21] | Kazemi F, Kiasat A R, Sarvestani E. Chin Chem Lett, 2008, 19: 1167
|
| [22] | Yang Y H, Liu S X, Li J Z, Tian X, Zhen X L, Han J R. Synth Commun, 2012, 42: 2540
|
| [23] | Gawaskar S, Schepmann D, Bonifazi A, Wünsch B. Bioorg Med Chem, 2014, 22: 6638
|
| [24] | Abdel-Magid A F, Carson K G, Haris B D, Maryanoff C A, Shah R D. J Org Chem, 1996, 61: 3849
|
| [25] | Kascheres A, Rodrigues R A F. Tetrahedron, 1996, 52: 12919
|
| [26] | Liu P S. J Org Chem, 1987, 52: 4717
|
| [27] | Shawe T T, Sheils C J, Gray S M, Conard J L. J Org Chem, 1994, 59: 5841
|
| [28] | Baruah B, Dutta M P, Boruah A, Prajapati D, Sandhu J S. Synlett, 1999: 409
|
| [29] | Kano S, Tanaka Y, Sugino E, Hibino S. Synthesis, 1980: 695
|
| [30] | Hoffman C, Tanke R S, Miller M J. J Org Chem, 1989, 54: 3750
|
| [31] | Itsuno S, Sakurai Y, Shimizu K, Ito K. J Chem Soc, Perkin Trans 1, 1990: 1859
|
| [32] | Itsuno S, Sakurai Y, Shimizu K, Ito K. J Chem Soc, Perkin Trans 1, 1989: 1548
|
| [33] | Aniz C U, Nair T D R. Open J Phys Chem, 2011, 1: 124
|
| [34] | Ghose J, Murthy K S R C. J Catal, 1996, 162: 359
|
| [35] | Jiang J, Yan M Y. Mater Lett, 2007, 61: 4276
|
| [36] | Yang J, Peng J, Liu K C, Guo R, Xu D L, Jia J P. J Hazard Mater, 2007, 143: 379
|
| [37] | Lv S S, Chen X G, Ye Y, Yin S H, Cheng J P, Xia M S. J Hazard Mater, 2009, 171: 634
|
| [38] | Zhou Z, Yan J, Wang Y X. Chem, 1998, 4: 23
|
| [39] | Yang G Q, Han B, Sun Z T, Yan L M, Wang X Y. Dyes Pigm, 2002, 55: 9
|
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