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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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Ce-Beta分子筛的制备及其催化性能
DOI: 10.1016/S1872-2067(14)60277-1, PP. 801-805
Keywords: Ce-Beta分子筛,后合成,脱铝,开环水合,环氧
Abstract:
？采用简单、易重现的两步后合成法成功制备了Ce-Beta分子筛.制备过程中,H-Beta分子筛首先经过脱铝处理得到Si-Beta分子筛,然后再以异丙醇铈为前驱体,通过干法浸渍的途径向Si-Beta分子筛引入Ce(IV).利用XRD,FT-IR,UV-Vis和1HMASNMR等对其结构进行了表征,结果表明,Ce(IV)物种以四配位的形式成功引入Beta分子筛的骨架,Ce原子进入分子筛骨架的机理通过DRIFT光谱得以证实.通过环氧化合物水合制备1,2-二醇反应对所制的Ce-Beta催化剂进行了催化性能评价.
| [1] | Corma A. Chem Rev, 1997, 97: 2373
|
| [2] | Cundy C S, Cox P A. Chem Rev, 2003, 103: 663
|
| [3] | Moliner M. Dalton Trans, 2014, 43: 4197
|
| [4] | Guo H C, Wang X S, Zou B S. Chin J Catal (郭洪臣, 王祥生, 邹本三. 催化学报), 1997, 18: 185
|
| [5] | Wu Y J, Wang J, Liu P, Zhang W, Gu J, Wang X J. J Am Chem Soc, 2010, 132: 17989
|
| [6] | Camblor M A, Corma A, Martínez A, Pérez-Pariente J. J Chem Soc, Chem Commun, 1992: 589
|
| [7] | Jappar N, Xia Q H, Tatsumi T. J Catal, 1998, 180: 132
|
| [8] | Gunther W R, Wang Y R, Ji Y W, Michaelis V K, Hunt S T, Griffin R G, Román-Leshkov Y. Nat Commun, 2012, 3: 1109
|
| [9] | Jinka K M, Lee S C, Park S E, Jasra R V. Stud Surf Sci Catal, 2008, 174B: 1187
|
| [10] | Nogier J P, Millot Y, Man P P, Shishido T, Che M, Dzwigaj S. J Phys Chem C, 2009, 113: 4885
|
| [11] | Li P, Liu G Q, Wu H H, Liu Y M, Jiang J G, Wu P. J Phys Chem C, 2011, 115: 3663
|
| [12] | Hammond C, Conrad S, Hermans I. Angew Chem Int Ed, 2012, 51: 11736
|
| [13] | Wolf P, Hammond C, Conrad S, Hermans I. Dalton Trans, 2014, 43: 4514
|
| [14] | Dijkmans J, Gabri？ls D, Dusselier M, de Clippel F, Vanelderen P, Houthoofd K, Malfliet A, Pontikes Y, Sels B F. Green Chem, 2013, 15: 2777
|
| [15] | Tang B, Dai W L, Sun X M, Guan N J, Li L D, Hunger M. Green Chem, 2014, 16: 2281
|
| [16] | Tang B, Dai W L, Wu G J, Guan N J, Li L D, Hunger M. ACS Catal, 2014, 4: 2801
|
| [17] | Janas J, Gurgul J, Socha R P, Shishido T, Che M, Dzwigaj S. Appl Catal B, 2009, 91: 113
|
| [18] | Dzwigaj S, Millot Y, Krafft J M, Popovych N, Kyriienko P. J Phys Chem C, 2013, 117: 12552
|
| [19] | Juttu G G, Lobo R F. Catal Lett, 1999, 62: 99
|
| [20] | Laha S C, Mukherjee P, Sainkar S R, Kumar R. J Catal, 2002, 207: 213
|
| [21] | Hunger M, Ernst S, Steuernagel S, Weitkamp J. Microporous Mater, 1996, 6: 349
|
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