|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
Co-ETS-10andCo-AM-6asactivecatalystsfortheoxidationofstyrenetostyreneoxideandbenzaldehydeusingmolecularoxygen
DOI: 10.1016/S1872-2067(15)60864-6, PP. 897-905
Keywords: Heterogeneouscatalysis,Epoxidation,Cobalt,C=Cactivation,Zeolite
Abstract:
？PristineETS-10andAM-6andtheirCo2+-exchangedformswereprepared,andtheircatalyticactivitiestowardtheoxidationofstyreneinoxygenatmospherewerestudiedindimethylformamide.ThecatalystsweredenotedasCo-E10-n(n=0,9,26,68,81)andCo-A6-m(m=0,8,23,63,79),wherenandmdenotethedegreeofCo2+exchange.Theproductsoftheoxidationprocesswereidentifiedasstyreneepoxide(E)andbenzaldehyde(B).Boththepristineforms,ETS-10(Co-E10-0)andAM-6(Co-A6-0),andCo2+-exchangedformsdisplayedcatalyticactivities.Withincreasingnorm,theconversion,andhencetherate,increased.Specifically,theratesvariedfrom6.1to12.5mmol·g-1·h-1withincreasingn(Co-E10-ncatalysts)andfrom5.4to12.4mmol·g-1·h-1withincreasingm(Co-A6-mcatalysts).Incontrast,theE/Bratiodecreasedwithincreasingnorm.Morespecifically,theE/Bratiodecreasedfrom2.1to0.1withincreasingnfrom0to81(Co-E10-ncatalysts)andfrom1.3to0.1withincreasingmfrom0to79(Co-A6-mcatalysts).Co-E10-9displayedthehighestEyieldandCo-A6-79generatedthehighestByield.Thehighestturnoverfrequencyobtainedwas36.3Co-1·h-1,whichwasthehighestoneobtainedamongthoseobtainedfortheCo2+-exchangedzeolitesandmesoporoussilicareferencematerialsstudiedinthiswork.
| [1] | Joergensen K A. Chem Rev, 1989, 89: 431
|
| [2] | Neumann R, Dahan M. Nature, 1997, 388: 353
|
| [3] | Hill C L. Nature, 1999, 401: 436
|
| [4] | Ishii Y, Sakaguchi S, Iwahama T. Adv Synth Catal, 2001, 343: 393
|
| [5] | Tang Q H, Wang Y, Liang J, Wang P, Zhang Q H, Wan H L. Chem Commun, 2004: 440
|
| [6] | Tang Q H, Zhang Q H, Wu H L, Wang Y. J Catal, 2005, 230: 384
|
| [7] | Sebastian J, Jinka K M, Jasra R V. J Catal, 2006, 244: 208
|
| [8] | Patil M V, Yadav M K, Jasra R V. J Mol Catal A, 2007, 277: 72
|
| [9] | Jinka K M, Pai S M, Newalkar B L, Choudary N V, Jasra R V. Catal Commun, 2010, 11: 638
|
| [10] | Cui H T, Zhang Y, Zhao L F, Zhu Y L. Catal Commun, 2011, 12: 417
|
| [11] | Xu G, Xia Q H, Lu X H, Zhang Q, Zhan H J, J Mol Catal A, 2007, 266: 180
|
| [12] | Qi B, Lu X H, Fang S Y, Lei J, Dong Y L, Zhou D, Xia Q H, J Mol Catal A, 2011, 334: 44
|
| [13] | Tang B, Lu X H, Zhou D, Lei J, Niu Z H, Fan J, Xia Q H. Catal Commun, 2012, 21: 68
|
| [14] | Tang B, Lu X H, Zhou D, Tian P, Niu Z H, Zhang J L, Chen X, Xia Q H. Catal Commun, 2013, 3: 42
|
| [15] | Zhou D, Tang B, Lu X H, Wei X L, Li K, Xia Q H. Catal Commun, 2014, 45: 124
|
| [16] | Wei X L, Lu X H, Ma X T, Peng C, Jiang H Z, Zhou D, Xia Q H, Catal Commun, 2015, 61: 48
|
| [17] | Kuznicki S M. US Patent 4853202. 1989
|
| [18] | Anderson M W, Terasaki O, Ohsuna T, Philippou A, MacKay S P, Ferreira A, Rocha J, Lidin S. Nature, 1994, 367: 347
|
| [19] | Anderson M W, Terasaki O, Ohsuna T, Malley P J O, Philippou A, MacKay S P, Ferreira A, Rocha J, Lidin S. Philos Mag B, 1995,71: 813
|
| [20] | Rocha J, Brandao P, Lin Z, Anderson M W, Alfredsson V, Terasaki O. Angew Chem Int Ed, 1997, 36: 100
|
| [21] | Datta S J, Yoon K B. Angew Chem Int Ed, 2010, 49: 4971
|
| [22] | Datta S J, Yoon K B. J Am Chem Soc, 2012, 134: 17202
|
| [23] | Jeong N C, Lee M H, Yoon K B. Angew Chem Int Ed, 2007, 46: 5868
|
| [24] | Datta S J, Yoon K B. Catal Today, 2013, 204: 60
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
