|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
多金核二氧化铈空心球用于硝基苯酚催化加氢
DOI: 10.1016/S1872-2067(14)60273-4, PP. 261-267
Keywords: 多金核,二氧化铈空心球,硝基苯酚,催化还原
Abstract:
？催化剂的微观结构在催化还原反应、有机物氧化反应及有机物转化反应中起着关键作用.本文利用无模板方法合成了多金核中空二氧化铈微球催化剂.将制备好的二氧化铈中空微球浸渍到一定浓度的氯金酸溶液中,然后多次洗涤除去表面吸附的氯金酸离子,最后通过硼氢化钠还原制成中空氧化铈微球包覆的多金核的核壳结构催化剂.将该核壳结构材料用于硝基苯酚加氢反应与金纳米粒子及氧化铈微球相比,多金核中空二氧化铈核壳结构表现出优越的活性和稳定性.通过这种浸渍洗涤再还原的简单方法合成的多金核二氧化铈催化剂有望应用于生物医药和能源环境等领域.
| [1] | Qi J, Zhao T B, Xu X, Li F Y, Sun G D. J Porous Mater, 2011, 18: 69
|
| [2] | Rodriguez J A, Ma S, Liu P, Hrbek J, Evans J, Pérez M. Science, 2007, 318: 1757
|
| [3] | Seh Z W, Liu S H, Low M, Zhang S Y, Liu Z L, Mlayah A, Han M Y. Adv Mater, 2012, 24: 2310
|
| [4] | Sun C W, Li H, Chen L Q. Energy Environ Sci, 2012, 5: 8475
|
| [5] | Jiang X, Hua J F, Deng H, Wu Z B. J Mol Catal A, 2014, 383-384: 188
|
| [6] | Fabris S, de Gironcoli S, Baroni S, Vicario G, Balducci G. Phys Rev B, 2005, 71: 041102
|
| [7] | Qi J, Zhao K, Li G D, Gao Y, Zhao H J, Yu R B, Tang Z Y. Nanoscale, 2014, 6: 4072
|
| [8] | Mogensen M, Lindegaard T, Rud Hansen. J Electrochem Soc, 1994, 141: 2122
|
| [9] | Zhang Q, Lee I, Joo J B, Zaera F, Yin Y D. Acc Chem Res, 2013, 46: 1816
|
| [10] | Liu S H, Han M Y. Chem Asian J, 2009, 5: 36
|
| [11] | Schartl W. Adv Mater, 2000, 12: 1899
|
| [12] | Caruso F. Adv Mater, 2001, 13: 11
|
| [13] | Lee J, Park J C, Song H. Adv Mater, 2008, 20: 1523
|
| [14] | Huang X Q, Guo C Y, Zuo J Q, Zheng N F, Stucky G D. Small, 2009, 5: 361
|
| [15] | Arnal P M, Comotti M, Schüth F. Angew Chem Int Ed, 2006, 45: 8224
|
| [16] | Qi J, Chen J, Li G D, Li S X, Gao Y, Tang Z Y. Energy Environ Sci, 2012, 5: 8937
|
| [17] | Camellone M F, Fabris S. J Am Chem Soc, 2009, 131: 10473
|
| [18] | Zhang N, Fu X Z, Xu Y J. J Mater Chem, 2011, 21: 8152
|
| [19] | Wang X, Liu D P, Song S Y, Zhang H J. J Am Chem Soc, 2013, 135: 15864
|
| [20] | Deng Y H, Cai Y, Sun Z K, Liu J, Liu C, Wei J, Li W, Liu C, Wang Y, Zhao D Y. J Am Chem Soc, 2010, 132: 8466
|
| [21] | Zhang Z Y, Xiao F, Xi J B, Sun T, Xiao S, Wang H R, Wang S, Liu Y Q. Sci Rep, 2014, 4: 4053
|
| [22] | Zaera F. Chem Soc Rev, 2013, 42: 2746
|
| [23] | Li G D, Tang Z Y. Nanoscale, 2014, 6: 3995
|
| [24] | Mitsudome T, Mikami Y, Matoba M, Mizugaki T, Jitsukawa K, Kaneda K. Angew Chem Int Ed, 2012, 51: 136
|
| [25] | Galeano C, Gttel R, Paul M, Arnal P, Lu A, Schth F. Chem Eur J, 2011, 17: 8434
|
| [26] | Güttel R, Paul M, Galeano C, Schüth F. J Catal, 2012, 289: 100
|
| [27] | Wu X F, Song H Y, Yoon J M, Yu Y T, Chen Y F. Langmuir, 2009, 25: 6438
|
| [28] | Ma X, Zhao K, Tang H J, Chen Y, Lu C G, Liu W, Gao Y, Zhao H J, Tang Z Y. Small, 2014, 10: 4664
|
| [29] | Guan B Y, Wang T, Zeng S J, Wang X, An D, Wang D M, Cao Y, Ma D X, Liu Y L, Huo Q S. Nano Res, 2014, 7: 246
|
| [30] | Khan M M, Ansari S A, Ansari M O, Min B K, Lee J, Cho M H. J Phys Chem C, 2014, 118: 9477
|
| [31] | Jin Z, Xiao M D, Bao Z H, Wang P, Wang J F. Angew Chem Int Ed, 2012, 51: 6404
|
| [32] | Fan C M, Zhang L F, Wang S S, Wang D H, Lu L Q, Xu A W. Nanoscale, 2012, 4: 6835
|
| [33] | Li X Z, Zhu X H, Fang Y Y, Yang H L, Zhou X C, Chen W M, Jiao L X, Huo H F, Li R. J Mater Chem A, 2014, 2: 10485
|
| [34] | Xu P F, Yu R B, Ren H, Zong L B, Chen J, Xing X R. Chem Sci, 2014, 5: 4221
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
