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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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新型Br？nsted酸性离子液体催化二氧化碳与环氧化合物偶联反应
DOI: 10.1016/S1872-2067(14)60227-8, PP. 408-413
Keywords: 二氧化碳固定,偶联反应,酸性离子液体,环碳酸酯,哈米特酸度
Abstract:
？设计合成了一系列由碳链长度可调节的Br？nsted酸中心阳离子及Lewis碱中心阴离子构成的酸性离子液体,并应用于二氧化碳与环氧化合物的偶联反应合成环碳酸酯.考察了离子液体结构以及温度、压力和催化剂用量等参数的影响.结果表明,具有长碳链的离子液体表现出高催化活性及可重复使用性能.离子液体的酸性影响催化活性.
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