|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
小分子伯胺催化异噁唑有氧还原开环反应
DOI: 10.1016/S1872-2067(14)60200-X, PP. 204-208
Keywords: 有机催化,小分子伯胺,有氧还原开环,1-氨基-2-乙酰基蒽醌,绿色化学
Abstract:
？有机催化是催化领域的前沿.在水介质中,以水合肼作为还原剂研究了小分子有机胺催化3-甲基蒽醌-[1,2-c]-异噁唑有氧还原开环反应高效合成1-氨基-2-乙酰基蒽醌,详细考察了不同种类有机胺对异噁唑有氧还原开环反应的催化性能,发现小分子有机伯胺具有很好的还原开环催化性能.在1倍水合肼存在下室温反应3h,3-甲基蒽醌-[1,2-c]-异噁唑转化率和目标产物1-氨基-2-乙酰基蒽醌选择性均可达到97.2%.产物的分子结构经氢核磁谱和质谱得以确证.此外,提出了小分子有机伯胺催化3-甲基蒽醌-[1,2-c]-异噁唑有氧还原开环反应合成1-氨基-2-乙酰基蒽醌的可能反应机理.
| [1] | Zhang X S, Song X X, Li H, Zhang S L, Chen X B, Yu X H, Wang W. Angew Chem Int Ed, 2012, 51: 7282
|
| [2] | Akiba K, Kashiwagi K, Ohyama Y, Yamamoto Y, Ohkata K. J Am Chem Soc, 1985, 107: 2721
|
| [3] | Krasavin M, Busel A, Parchinsky V. Tetrahedron Lett, 2009, 50: 5945
|
| [4] | Zhao Z K, Li R Z, Li Y, Chen G T (赵忠奎, 李仁志, 李宇, 陈广涛). CN Patent 102603547A. 2013
|
| [5] | Epple G, Flohr H. DE Patent 2912570A1. 1979
|
| [6] | Wilke K. US Patent 1830152. 1931
|
| [7] | Li C S, Lacasse E. Tetrahedron Lett, 2002, 43: 3565
|
| [8] | Vasilevsky S F, Gornostaev L M, Stepanov A A, Arnold E V, Alabugin I V. Tetrahedron Lett, 2007, 48: 1867
|
| [9] | Churykau D H, Zinovich V G, Kulinkovich O G. Synlett, 2004, 11: 1949
|
| [10] | Buechi G, Vederas J C. J Am Chem Soc, 1972, 27: 9128
|
| [11] | Konwar D, Boruah R C, Sandhu J S. Chem Ind, 1989, (6): 191
|
| [12] | Auricchio S, Bini A, Pastormerlo E, Truscello A M. Tetrahedron, 1997, 53: 10911
|
| [13] | Kijima M, Nambu Y, Endo T. J Org Chem, 1985, 50: 1140
|
| [14] | Mohatt J L, Hu L H, Finneran K T, Strathmann T J. Environ Sci Technol, 2011, 45: 4793
|
| [15] | Angibaud P R, Venet M G, Filliers W, Broeckx R, Ligny Y A, Muller P, Poncelet V S, End D W. Eur J Org Chem, 2004, 2004: 479
|
| [16] | Fan X S, Zhang Y M. Tetrahedron Lett, 2002, 43: 7001
|
| [17] | Natale N R. Tetrahedron Lett, 1982, 23: 5009
|
| [18] | Konwar D, Boruah R C, Sandhu J S, Baruah J N. Synth Commun, 1984, 14: 1053
|
| [19] | Olah G A, Narang S C. Tetrahedron, 1982, 38: 2225
|
| [20] | Walker G N. J Org Chem, 1962, 27: 1929
|
| [21] | Oster T A, Harris T M. J Org Chem, 1983, 48: 4307
|
| [22] | Caplan J F, Zheng R J, Blanchard J S, Vederas J C. Org Lett, 2000, 2: 3857
|
| [23] | Charest M G, Siegel D R, Myers A G. J Am Chem Soc, 2005, 127: 8292
|
| [24] | Zhao Z K, Li R Z, Li Y. Chin J Catal (赵忠奎, 李仁志, 李宇. 催化学报), 2014, 35: 319
|
| [25] | MacMillan D W C. Nature, 2008, 455: 304
|
| [26] | Nicewicz D A, MacMillan D W C. Science, 2008, 322: 77
|
| [27] | Lamani M, Guralamata R S, Prabhu K R. Chem Commun, 2012, 48: 6583
|
| [28] | de Vries J G, Mrsic N. Catal Sci Technol, 2011, 1: 51
|
| [29] | Imada Y, Kitagawa T, Ohno T, Iida H, Naota T. Org Lett, 2010, 12: 32
|
| [30] | Chen C X, Xu R, Li B. Sci China B, 2012, 55: 1257
|
| [31] | Zhao Z K, Li R Z, Li Y. ScienceJet, 2013, 2: 41
|
| [32] | Chen Q, Liang J Y, Wang S L, Wang D, Wang R. Chem Commun, 2013, 49: 1657
|
| [33] | Kano T, Song S Y, Kubota Y L, Maruoka K. Angew Chem Int Ed, 2012, 51: 1191
|
| [34] | Liu J, Yang Z G, Wang Z, Wang F, Chen X H, Liu X H, Feng X M, Su Z S, Hu C W. J Am Chem Soc, 2008, 130: 5654
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
