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OALib Journal期刊
ISSN: 2333-9721
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经由Domino脱HCl/Pd(OAc)2催化的Heck反应合成查尔酮
DOI: 10.1016/S1872-2067(14)60247-3, PP. 78-85
Keywords: β-氯代烷基芳基酮,Heck反应,烯酮,Domino反应,查尔酮
Abstract:
？通过Domino脱HCl/Pd(OAc)2催化的Heck反应实现了β-氯代烷基芳基酮、酯和酰胺与卤代芳烃的交叉偶联反应,高效合成了查尔酮类化合物.利用原位生成烯酮为中间体进行反应的策略,减少副反应的发生,从而提高反应的效率.该方法对各种官能团的容忍性好,为从氯代烷烃出发直接合成查尔酮类化合物提供了一条新途径.
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