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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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Cu催化吲哚啉的炔丙基烷基化/脱氢对映选择性合成手性N-炔丙基吲哚化合物
DOI: 10.1016/S1872-2067(14)60230-8, PP. 86-92
Keywords: 不对称合成,铜,炔丙基取代,脱氢,N-炔丙基吲哚
Abstract:
？基于吲哚啉的Cu催化不对称炔丙基烷基化及DDQ脱氢策略,成功合成了手性N-炔丙基吲哚化合物.通过使用一个结构刚性的酮亚胺三齿P,N,N-配体,反应获得了很好的对映选择性.该方法反应条件温和、底物适用范围广、产物收率高、立体选择性好,为手性N-炔丙基吲哚化合物的合成提供了一条简捷、高效的新途径.
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