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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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海蛎壳粉废弃物负载CuCl2作为高效、廉价以及可回收催化剂合成炔胺类化合物
DOI: 10.1016/S1872-2067(14)60195-9, PP. 2006-2013
Keywords: 炔胺类化合物,A3偶联反应,海蛎壳废弃物,微波辐射,绿色化学
Abstract:
？发展了一种经济、简单的海蛎壳粉负载的CuCl2异相催化剂OSP-CuCl2,用来催化醛-炔-胺之间的A3偶联反应.OSP-CuCl2容易通过简单的方法从海蛎壳粉以及CuCl2制备,且显示出高的催化活性以及良好的可循环回收性.在微波辅助以及无溶剂条件下,以OSP-CuCl2为催化剂,能够以高产物收率制备出一系列炔胺类化合物.OSP-CuCl2可通过简单的过滤方式进行回收,并至少可循环使用6次.初步放大实验表明,炔胺类化合物能够以150mmol的规模制备(87%收率).
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