|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
PVP-NiB非晶态催化剂的制备和催化苯酚及其衍生物加氢反应性能
DOI: 10.1016/S1872-2067(14)60203-5, PP. 1793-1799
Keywords: 镍,苯酚,催化加氢,非晶态催化剂
Abstract:
？以聚乙烯吡咯烷酮(PVP)为稳定剂,采用化学还原法制备了PVP-NiB非晶态催化剂,通过红外光谱、X射线衍射、透射电子显微镜和电感耦合等离子体光谱对催化剂进行了表征.结果表明,PVP不仅能够提高NiB纳米颗粒的分散度,而且对其起到稳定作用;将该催化剂首次应用于苯酚及其衍生物的催化加氢反应,在水相体系中,30℃及氢气压力0.2MPa时,苯酚的转化率和环己醇的选择性都能够达到99.9%;酚类衍生物加氢反应结果发现,该催化剂有利于环己醇类物质的生成,初步考察了PVP-NiB非晶态催化剂的构效关系.
| [1] | Chary K V R, Naresh D, Vishwanathan V, Sadakane M, Ueda W. Catal Commun, 2007, 8: 471
|
| [2] | Shore S G, Ding E, Park C, Keane M A. Catal Commun, 2002, 3: 77
|
| [3] | Mahata N, Vishwanathan V. Ind J Chem A, 1998, 37: 652
|
| [4] | Scirè S, Minicò S, Crisafulli C. Appl Catal A, 2002, 235, 21
|
| [5] | Chen A B, Zhao G Y, Chen J Z, Chen L M, Yu Y F. RSC Adv, 2013, 3: 4171
|
| [6] | Cheng H Y, Liu R X, Wang Q, Wu C Y, Yu Y C, Zhao F Y. New J Chem, 2012, 36: 1085
|
| [7] | Xiang Y Z, Ma L, Lu C S, Zhang Q F, Li X N. Green Chem, 2008, 10: 939
|
| [8] | Park H W, Kim J K, Hong U G, Lee Y J, Song J H, Song I K. Appl Catal A, 2013, 453: 287
|
| [9] | Yu Y X, Xu Y, Wang T J, Ma L L, Zhang Q, Zhang X H, Zhang X. J Fuel Chem Technol (于玉肖, 徐莹, 王铁军, 马隆龙, 张琦, 张兴华, 张雪. 燃料化学学报), 2013, 41: 443
|
| [10] | Wang Y, Yao J, Li H R, Su D S, Antonietti M. J Am Chem Soc, 2011, 133: 2362
|
| [11] | Rode C V, Joshi U D, Sato O, Shirai M. Chem Commun, 2003: 1960
|
| [12] | Liu H Z, Jiang T, Han B X, Liang S G, Zhou Y X. Science, 2009, 326: 1250
|
| [13] | Wang W Y, Yang Y Q, Luo H, Peng H Z, He B, Liu W Y. Catal Commun, 2011, 12: 1275
|
| [14] | Li H, Liu J, Xie S H, Qiao M H, Dai W L, Li H X. J Catal, 2008, 259: 104
|
| [15] | Zhuang L, Li H X, Dai W L, Qiao M H. Chem Lett, 2003, 32: 1072
|
| [16] | Li H, Liu J L, Li H X. Mater Lett, 2008, 62: 297
|
| [17] | Yu Y X, Zhang X H, Wang T J, Xu Y, Ma L L, Zhang Q, Zhang L M. Chem J Chin Univ, 2013, 34: 2178
|
| [18] | Liaw B J, Chiang S J, Tsai C H, Chen Y Z. Appl Catal A, 2005, 284: 239
|
| [19] | Zhang Z T, Zhao B, Hu L M. J Solid State Chem, 1996, 121: 105
|
| [20] | Koo C M, Ham H T, Choi M H, Kim S O, Chung I J. Polymer, 2003, 44: 681
|
| [21] | Roucoux A, Schulz J, Patin H. Chem Rev, 2002, 102: 3757
|
| [22] | Dai W L, Li H X, Cao Y, Qiao M H, Fan K N, Deng J F. Langmuir, 2002, 18: 9605
|
| [23] | Chen Y Z, Liaw B J, Chiang S J. Appl Catal A, 2005, 284: 97
|
| [24] | Deng J F, Li H, Wang W. Catal Today, 1999, 51: 113
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
