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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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Carbonnanohybridsusedascatalystsandemulsifiersforreactionsinbiphasicaqueous/organicsystems
DOI: 10.1016/S1872-2067(14)60119-4, PP. 798-806
Keywords: Carbonnanomaterials,Nanohybrids,Emulsions,Biphasicaqueous/organicmixtures,Catalysisatwater/oilinterface,Biomassconversion,Fischer-Tropschsynthesis
Abstract:
？Thismini-reviewsummarizessomenovelaspectsofreactionsconductedinaqueous/organicemulsionsstabilizedbycarbonnanohybridsfunctionalizedwithcatalyticspecies.Carbonnanohybridsrepresentafamilyofsolidcatalyststhatnotonlycanstabilizewater-oilemulsionsinthesamefashionasPickeringemulsions,butalsocatalyzereactionsattheliquid/liquidinterface.Severalexamplesarediscussedinthismini-review.Theyinclude(a)aldolcondensation-hydrodeoxygenationtandemreactionscatalyzedbybasic(MgO)andmetal(Pd)catalysts,respectively;(b)Fischer-Tropschsynthesiscatalyzedbycarbon-nanotube-supportedRu;and(c)emulsionpolymerizationofstyrenefortheproductionofconductivepolymercomposites.Conductingthesereactionsinemulsiongeneratesimportantadvantages,suchasincreasedliquid/liquidinterfacialareathatconsequentlymeansfastermasstransferratesofmoleculesbetweenthetwophases,effectiveseparationofproductsfromthereactionmixturebydifferencesinthewater-oilsolubility,andsignificantchangesinproductselectivitythatcanbeadjustedbymodifyingtheemulsioncharacteristics.
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