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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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Ni/SAPO-11催化剂上棕榈油加氢脱氧制异构烃燃料
DOI: 10.1016/S1872-2067(12)60710-4, PP. 748-756
Keywords: 棕榈油,加氢脱氧,烃,异构化,协同效应
Abstract:
？采用水热法合成了小粒径、具有介孔结构的SAPO-11分子筛.采用浸渍法制备了不同Ni负载量的Ni/SAPO-11催化剂.并采用X射线衍射，扫描电镜，N2物理吸附-脱附，NH3程序升温脱附，热重和H2化学吸附技术对该类催化剂的物理化学性质进行了详细表征.结果表明，SAPO-11较大表面积和介孔结构可分散Ni，使得Ni粒子尺寸较小.在棕榈油加氢脱氧制备液体烃类燃料反应中，液体烷烃产物由相关脂肪酸中间产物的直接加氢脱氧和脱羰-加氢脱氧两种途径产生.Ni/SAPO-11催化剂的弱/中强酸性质及其匹配的金属-酸双功能可显著抑制积炭反应，提高催化剂的寿命，液体烷烃收率高达70%，异构烷烃选择性超过80%.
| [1] | Smith B, Greenwell H C, Whiting A. Energy Environ Sci, 2009, 2: 262
|
| [2] | Lotero E, Liu Y, Lopez D E, Suwannakarn K, Bruce D A, Goodwin J G Jr. Ind Eng Chem Res, 2005, 44: 5353
|
| [3] | Senol O I, Viljava T R, Krause A O I. Catal Today, 2005, 100: 331
|
| [4] | Guzman A, Torres J E, Prada L P, Nu？ez M L. Catal Today, 2010, 156: 38
|
| [5] | Gong S F, Shinozaki A, Shi M L, Qian E W. Energy Fuels, 2012, 26: 2394
|
| [6] | Gong S F, Shinozaki A, Qian E W. Ind Eng Chem Res, 2012, 51: 13953
|
| [7] | Hancsók J, Krár M, Magyar S, Boda L, Holló A, Kalló D. Stud Surf Sci Catal, 2007, 170: 1605
|
| [8] | Liu G Y, Tian P, Xia Q H, Liu Z M. J Natur Gas Chem, 2012, 21: 431
|
| [9] | Akhmedov V M, Al-Khowaiter S H. Catal Rev Sci Eng, 2007, 49: 33
|
| [10] | Kikhtyanin O V, Rubanov A E, Ayupov A B, Echevsky G V. Fuel, 2010, 89: 3085
|
| [11] | Zuo H L, Liu Q Y, Wang T J, Ma L L, Zhang Q, Zhang Q. Energy Fuels, 2012, 26: 3747
|
| [12] | Fan Y, Xiao H, Shi G, Liu H Y, Bao X J. J Catal, 2012, 285: 251
|
| [13] | Elangovan S P, Hartmann M. J Catal, 2003, 217: 388
|
| [14] | Walendziewski J, Pniak B. Appl Catal A, 2003, 250: 39
|
| [15] | Takai Y, Ueno A, Kotera Y. Bull Chem Soc Jpn, 1983, 56: 2941
|
| [16] | Peng B X, Yao Y, Zhao C, Lercher J A. Angew Chem Int Ed, 2012, 51: 2072
|
| [17] | Senol O I, Ryymin E M, Viljava T R, Krause A O I. J Mol Catal A, 2007, 268: 1
|
| [18] | Lestari S, M？ki-Arvela P, Er？nen K, Beltramini J, Max Lu G Q, Murzin D Y. Catal Lett, 2010, 134: 250
|
| [19] | Agarwal A K. Prog Energy Combust Sci, 2007, 33: 233
|
| [20] | Chiappero M, Do P T M, Crossley S, Lobban L L, Resasco D E. Fuel, 2011, 90: 1155
|
| [21] | Kumar R, Rana B S, Tiwari R, Verma D, Kumar R, Joshi R K, Garg M O, Sinha A K. Green Chem, 2010, 12: 2232
|
| [22] | M？ki-Arvela P, Sn？re M, Er？nen K, Myllyoja J, Murzin D Y. Fuel, 2008, 87: 3543
|
| [23] | Hancsók J, Krár M, Magyar S, Boda L, Holló A, Kalló D. Microporous Mesoporous Mater, 2007, 101: 148
|
| [24] | Yang Y X, Ochoa-Hernández C, de la Pe？a O'Shea V A, Coronado J M, Serrano D P. ACS Catal, 2012, 2: 592
|
| [25] | Han J X, Duan J Z, Chen P, Lou H, Zheng X M, Hong H P. ChemSusChem, 2012, 5: 727
|
| [26] | Snare M, Kubickova I, Maki-Arvela P, Eranen K, Murzin D Y. Ind Eng Chem Res, 2006, 45: 5708
|
| [27] | Pastore H O, Coluccia S, Marchese L. Ann Rev Mater Res, 2005, 35: 351
|
| [28] | Verma D, Kumar R, Rana B S, Sinha A K. Energy Eviron Sci, 2011, 4: 1667
|
| [29] | Han J X, Sun H, Ding Y Q, Lou H, Zheng X M. Green Chem, 2010, 12: 463
|
| [30] | de Brimont M R, Dupont C, Daudin A, Geantet C, Raybaud P. J Catal, 2012, 286: 153
|
| [31] | Ryymin E M, Honkela M L, Viljava T R, Krause A O I. Appl Catal A, 2009, 358: 42
|
| [32] | Turek T, Trimm D L, Cant N W. Catal Rev Sci Eng, 1994, 36: 645
|
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