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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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Highlyselectiveformationofiminescatalyzedbysilvernanoparticlessupportedonalumina
DOI: 10.1016/S1872-2067(14)60033-4, PP. 670-676
Keywords: Heterogeneouscatalysis,Silvernanoparticle,Oxidativedehydrogenation,Alcohol,Aldehyde,Imine
Abstract:
？TheoxidativedehydrogenationofalcoholstoaldehydescatalyzedbyAgnanoparticlessupportedonAl2O3wasstudied.Thecatalystpromotedthedirectformationofiminesbytandemoxidativedehydrogenationandcondensationofalcoholsandamines.Thereactionswereperformedundermildconditionsandaffordedtheiminesinhighyield(upto99%)withoutanybyproductsotherthanH2O.Thehighestactivitywasobtainedover5wt%Ag/Al2O3intoluenewithairasoxidant.Thereactionswerealsoperformedunderoxidant-freeconditionswherethereactionwasdriventotheproductsidebytheproductionofH2inthegasphase.TheuseofanefficientandselectiveAgcatalystfortheoxidativedehydrogenationofalcoholinthepresenceofaminesgivesanewgreenreactionprotocolforiminesynthesis.
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