OALib Journal期刊
SulfonicacidheterogeneouscatalystsfordehydrationofC6-monosaccharidesto5-hydroxymethylfurfuralindimethylsulfoxide
DOI: 10.1016/S1872-2067(14)60020-6
Keywords: Fructose ,Glucose ,5-Hydroxymethylfurfural ,Dimethylsulfoxide ,Responsesurfacemethodology ,Sulfonicacid
Abstract:
？Sulfonicacid-functionalizedheterogeneouscatalystshavebeenevaluatedinthecatalyticdehydrationofC6monosaccharidesinto5-hydroxymethylfurfural(HMF)usingdimethylsulfoxide(DMSO)assolvent.SulfoniccommercialresinAmberlyst-70wasthemostactivecatalyst,whichwasascribedtoitshigherconcentrationofsulfonicacidsitesascomparedwiththeothercatalysts,anditgave93mol%yieldofHMFfromfructosein1h.Withglucoseasthestartingmaterial,whichisamuchmoredifficultreaction,thereactionconditions(time,temperature,andcatalystloading)wereoptimizedforAmberlyst-70byaresponsesurfacemethodology,whichgaveamaximumHMFyieldof33mol%at147℃with23wt%catalystloadingbasedonglucoseand24hreactiontime.DMSOpromotesthedehydrationofglucoseintoanhydroglucose,whichactsasareservoirofthesubstratetofacilitatetheproductionofHMFbyreducingsidereactions.Catalystreusewithoutaregenerationtreatmentshowedagradualbutnotverysignificantdecayincatalyticactivity.
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