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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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金属卤化物促进糖类催化转化制备5-羟甲基糠醛
DOI: 10.1016/S1872-2067(14)60012-7, PP. 496-500
Keywords: 糖类化合物,5-羟甲基糠醛,金属卤化物,催化
Abstract:
？研究了碱金属卤化物对AlCl3催化葡萄糖转化制备5-羟甲基糠醛（HMF）的促进作用.结果表明，NaF对反应有显著抑制作用，而NaI和NaBr对反应有显著促进作用，而且NaI比NaBr的促进效果更明显.在N，N-二甲基乙酰胺（DMAC）中，以NaI为添加剂，130℃反应15min，AlCl3催化葡萄糖转化制备HMF，葡萄糖转化率由71%提高到86%，HMF收率由36%提高到62%.AlCl3-NaI-DMAC体系也可用于果糖、甘露糖等单糖，蔗糖、麦芽糖、纤维二糖等二糖，以及菊粉等多糖的转化.以蔗糖为原料，HMF收率可达63%.
| [1] | Zhou C H, Xia X, Lin C X, Tong D S, Beltramini J. Chem Soc Rev, 2011, 40: 5588
|
| [2] | Van Putten R J, Van Der Waal J C, De Jong E, Rasrendra C B, Heeres H J, De Vries J G. Chem Rev, 2013, 113: 1499
|
| [3] | Rosatella A A, Simeonov S P, Frade R F M, Afonso C A M. Green Chem, 2011, 13: 754
|
| [4] | Ma J P, Yu W Q, Wang M, Jia X Q, Lu F, Xu J. Chin J Catal (马继平, 于维强, 王敏, 贾秀全, 路芳, 徐杰. 催化学报), 2013, 34: 492
|
| [5] | Nie J F, Xie J H, Liu H C. Chin J Catal (聂俊芳, 解佳翰, 刘海超. 催化学报), 2013, 34: 871
|
| [6] | Ma J P, Wang M, Du Z T, Chen C, Gao J, Xu J. Polym Chem, 2012, 3: 2346
|
| [7] | Che P H, Lu F, Zhang J J, Huang Y Z, Nie X, Gao J, Xu J. Bioresour Technol, 2012, 119: 433
|
| [8] | Cai J Y, Ma H, Zhang J J, Song Q, Du Z T, Huang Y Z, Xu J. Chem Eur J, 2013, 19: 14215
|
| [9] | Qi X H, Guo H X, Li L Y, Smith R L. ChemSusChem, 2012, 5: 2215
|
| [10] | Stahlberg T, Fu W J, Woodley J M, Riisager A. ChemSusChem, 2011, 4: 451
|
| [11] | Roman-Leshkov Y, Chheda J N, Dumesic J A. Science, 2006, 312: 1933
|
| [12] | Wang L, Zhang J, Zhu L F, Meng X J, Xiao F S. J Energy Chem, 2013, 22: 241
|
| [13] | Duquesnoy E, Castola V, Casanova J. Carbohydr Res, 2008, 343: 893
|
| [14] | Horvat J, Klaic B, Metelko B, Sunjic V. Tetrahedron Lett, 1985, 26: 2111
|
| [15] | Yeh T M, Dickinson J G, Franck A, Linic S, Thompson L T, Savage P E. J Chem Technol Biotechnol, 2013, 88: 13
|
| [16] | Gallezot P. Chem Soc Rev, 2012, 41: 1538
|
| [17] | Du Z T, Ma J P, Wang F, Liu J X, Xu J. Green Chem, 2011, 13: 554
|
| [18] | Ma J P, Du Z T, Xu J, Chu Q H, Pang Y. ChemSusChem, 2011, 4: 51
|
| [19] | Ma J P, Pang Y, Wang M, Xu J, Ma H, Nie X. J Mater Chem, 2012, 22: 3457
|
| [20] | Ma J P, Yu X F, Xu J, Pang Y. Polymer, 2012, 53: 4145
|
| [21] | Chen J Z, Lu F, Zhang J J, Yu W Q, Wang F, Gao J, Xu J. ChemCatChem, 2013, 5: 2822
|
| [22] | Jia X Q, Ma J P, Che P H, Lu F, Miao H, Gao J, Xu J. J Energy Chem, 2013, 22: 93
|
| [23] | Karinen R, Vilonen K, Niemelae M. ChemSusChem, 2011, 4: 1002
|
| [24] | Zhao H B, Holladay J E, Brown H, Zhang Z C. Science, 2007, 316: 1597
|
| [25] | Yong G, Zhang Y G, Ying J. Angew Chem Int Ed, 2008, 47: 9345
|
| [26] | Zhang Z H, Wang Q, Xie H B, Liu W J, Zhao Z B. ChemSusChem, 2011, 4: 131
|
| [27] | Hu S Q, Zhang Z F, Song J L, Zhou Y X, Han B X. Green Chem, 2009, 11: 1746
|
| [28] | Beckerle K, Okuda J. J Mol Catal A, 2012, 356: 158
|
| [29] | Rasrendra C B, Soetedjo J N M, Makertihartha I G B N, Adisasmito S, Heeres H J. Top Catal, 2012, 55: 543
|
| [30] | Yan H P, Yang Y, Tong D M, Xiang X, Hu C W. Catal Commun, 2009, 10: 1558
|
| [31] | Ren Q H, Huang Y Z, Ma H, Wang F, Gao J, Xu J. Bioresources, 2013, 8: 1563
|
| [32] | Binder J B, Raines R T. J Am Chem Soc, 2009, 131: 1979
|
| [33] | Lewkowski J. Arkivoc, 2001, 2: 17
|
| [34] | Fagnou K, Lautens M. Angew Chem Int Ed, 2002, 41: 26
|
| [35] | Maruoka K, Ooi T. Chem Eur J, 1999, 5: 829
|
| [36] | Roslund M U, T？htinen P, Niemitz M, Sj？holm R. Carbohydr Res, 2008, 343: 101
|
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