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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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AvoltammetricsensorwithamultiwallcarbonnanotubepasteelectrodeandnaphtholgreenasamediatorforthedeterminationofN-actylcysteineinthepresenceoftryptophan
DOI: 10.1016/S1872-2067(14)60019-X, PP. 501-508
Keywords: N-actylcysteine,Tryptophan,Multiwallcarbonnanotube,Naphtholgreen,Sensor
Abstract:
？AmultiwallcarbonnanotubemodifiedelectrodepreparedbyincorporatingmultiwallcarbonnanotubesintheelectrodeofasensorandnaphtholgreenasahomogeneousmediatorwasusedasavoltammetricsensorforthedeterminationofN-actylcysteine(N-AC)inthepresenceoftryptophan(Trp).ThevoltammogramsofdifferentialpulsevoltammetryofN-ACinamixturewithTrpwereseparatedfromeachotherbyapotentialdifferenceof200mV,whichallowedthedeterminationofbothN-ACandTrpsimultaneously.Undertheoptimumconditions,theelectrocatalyticcurrentsincreasedlinearlywithN-ACconcentrationintherangeof0.25-400μmol/L(twolinearsegmentswithdifferentslopes).ThedetectionlimitforN-ACwas0.08μmol/L.Thekineticparametersofthesystemweredeterminedusingelectrochemicalmethods.ThemethodwasappliedforthedeterminationofN-ACindrugandurinesamples.
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