|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
AnelectrodewithNi(Ⅱ)loadedanalcimezeolitecatalystfortheelectrooxidationofmethanol
DOI: 10.1016/S1872-2067(14)60002-4, PP. 383-390
Keywords: Analcimezeolite,Modifiedelectrode,Methanol,Cyclicvoltammetry,Electrocatalyticoxidation
Abstract:
？Thereisahighovervoltageintheoxidationofmethanolinfuelcells,andsomodifiedelectrodesareusedtodecreaseit.AmodifiedelectrodethatusedNi(Ⅱ)loadedanalcimezeolitetocatalyzetheelectrooxidationofmethanolinalkalinesolutionwasproposed.Analcimezeolitewassynthesizedbyhydrothermalsynthesis,andNi(Ⅱ)ionswereincorporatedintotheanalcimestructure,whichwasthenmixedwithcarbonpastetopreparemodifiedelectrode.Theelectrocatalyticoxidationofmethanolonthesurfaceofthemodifiedelectrodeinalkalinesolutionwasinvestigatedbycyclicvoltammetryandchronoamperometry.Theeffectsofthescanrateofthepotential,concentrationofmethanol,andamountofzeolitewereinvestigated.Therateconstantforthecatalyticreactionofmethanolwas6×103cm3mol-1s-1frommeasurementsusingchronoamperometry.Theproposedelectrodesignificantlyimprovedtheelectrontransferrateanddecreasedtheoverpotentialformethanoloxidation.
| [1] | Abdel Rahim M A, Abdel Hameed R M, Khalil M W. J Power Sources, 2004, 134: 160
|
| [2] | Morallón E, Cases F J, Vázquez J L, Aldaz A. Electrochim Acta, 1992, 37: 1883
|
| [3] | Biswas P C, Nodasaka Y, Enyo M. J Appl Electrochem, 1996, 26: 30
|
| [4] | Jiang Y X, Zou M Z, Yuan K, Xu H D. Electroanalysis, 1999, 11: 254
|
| [5] | Pushparaj H, Mani G, Muthiahpillai P, Velayutham M, Park Y K, Choi W C, Jang H T. Chin J Catal (催化学报), 2013, 34: 294
|
| [6] | Pepe F, De Gennaro B, Aprea P, Caputo D. Chem Eng J, 2013, 219: 37
|
| [7] | Mu X H, Wang D Z, Wang Y R, Lin M, Cheng S B, Shu X T. Chin J Catal (催化学报), 2013, 34: 69
|
| [8] | Zhou X Z, Liu Y, Meng X J, Shen B J, Xiao F S. Chin J Catal (催化学报), 2013, 34: 1504
|
| [9] | Deer W A, Howie R A, Zussman J. An Introduction to the Rock-Forming Minerals. Longman Scientic & Technical, Harlow, Essex, UK, 1992
|
| [10] | Taher M A, Mostafavi A, Mohammadi Mobarakeh S Z. J Anal Chem, 2007, 62: 1022
|
| [11] | Afzali D, Mostafavi A, Taher M A, Moradian A. Talanta, 2007, 71: 971
|
| [12] | Afzali D, Taher M A, Mostafavi Ali, Khayatzadeh Mahani M. J AOAC Int, 2005, 88: 842
|
| [13] | Shaw B R, Creasy K E, Lanczycki C J, Sargeant J A, Tirhado M. J Electrochem Soc, 1988, 135: 869
|
| [14] | Senaratne C, Zhang J, Baker M D, Bessel C A, Rolison D R. J Phys Chem, 1996, 100: 5849
|
| [15] | Bessel C A, Rolison D R. J Am Chem Soc, 1997, 119: 12673
|
| [16] | Afzali D, Mostafavi A, Taher M A, Rezaeipour E, Khayatzadeh Mahani M. Anal Sci, 2005, 21: 383
|
| [17] | Azizi S N, Ghasemi S, Chiani E. Electochim Acta, 2013, 88: 463
|
| [18] | Fakeeha A H, Khan W U, AL-Fatesh A S, Abasaeed A E. Chin J Catal (催化学报), 2013, 34: 764
|
| [19] | Ren L M, Zhang Y B, Zeng S J, Zhu L F, Sun Q, Zhang H Y, Yang C G, Meng X J, Yang X G, Xiao F S. Chin J Catal (催化学报), 2012, 33: 92
|
| [20] | Guzmán-Vargas A, Oliver-Tolentino M A, Lima E, Flores-Moreno J. Electrochim Acta, 2013, 108: 583
|
| [21] | Taran O P, Yashnik S A, Ayusheev A B, Piskun A S, Prihod'ko R V, Ismagilov Z R, Goncharuk V V, Parmon V N. Appl Catal B, 2013, 140-141: 506
|
| [22] | Azizi S N, Ehsani Tilami S. Microporous Mesoporous Mater, 2013, 167: 89
|
| [23] | Vertes G, Horanyi G, Nagi F. Acta Chim Acad Sci Hung, 1971, 67: 145
|
| [24] | Fleischmann M, Korinek K, Pletcher D. J Electroanal Chem Interfacial Electrochem, 1971, 31: 39
|
| [25] | Azizi S N, Ehsani Tilami S. Z Anorg Allg Chem, 2009, 635: 2660
|
| [26] | Harada K, Tanaka K, Nagashima K. Am Mineral, 1972, 57: 924
|
| [27] | Bessel C A, Rolison D R. J Phys Chem B, 1997, 101: 1148
|
| [28] | Laviron E. J Electroanal Chem Interfacial Electrochem, 1979, 101: 19
|
| [29] | Luo H X, Shi Z J, Li N Q, Gu Z N, Zhuang Q K. Anal Chem, 2001, 73: 915
|
| [30] | Zheng L, Song J F. J Solid State Electrochem, 2010, 14: 43
|
| [31] | Yi Q F, Zhang J J, Huang W, Liu X P. Catal Commun, 2007, 8: 1017
|
| [32] | Bindler F, Vages E, Laugel P. Food Addit Contam, 1988, 5: 343
|
| [33] | Baratz B, Quellette R, Park W, Stokes B. Mechanical, Thermal and Chemical Storage of Energy. Pennsylvania: Hutchinson Ross, 1981
|
| [34] | Lima A, Coutanceau C, Leger J M, Lamy C. J Appl Electrochem, 2001, 31: 379
|
| [35] | Parsons R, Vander Noot T. J Electroanal Chem Interfacial Electrochem, 1988, 257: 9
|
| [36] | He Y P, Liu M, Dai C Y, Xu S T, Wei Y X, Liu Z M, Guo X W. Chin J Catal (催化学报), 2013, 34: 1148
|
| [37] | Petrucelli G C, Kawachi E Y, Kubota L T, Bertran C A. Anal Commun, 1996, 33: 227
|
| [38] | Shi X Y, Liu F D, Shan W P, He H. Chin J Catal (催化学报), 2012, 33: 454
|
| [39] | Wang J Y, Xia H A, Ju X H, Fan F T, Feng Z C, Li C. Chin J Catal (催化学报), 2013, 34: 876
|
| [40] | Zhang X Y, Shen Q, He C, Ma C Y, Cheng J, Hao Z P. Catal Commun, 2012, 18: 151
|
| [41] | Raoof J B, Azizi N, Ojani R, Ghodrati S, Abrishamkar M, Chekin F. Int J Hydrogen Energy, 2011, 36: 13295
|
| [42] | Pechar F, Rykl D. Chem Pap, 1983, 37: 757
|
| [43] | Bard A J, Faulkner L R. Bard A J. Electrochemical Methods, Fundamentals and Applications. New York: Wiley, 2001
|
| [44] | Taraszewska J, Roslonek G. J Electroanal Chem, 1994, 364: 209
|
| [45] | Robertson P M. J Electroanal Chem, 1980, 111: 97
|
| [46] | Liu B, Zhang Y S, Yuan H T, Yang H B, Yang E D. Int J Hydrogen Energy, 2000, 25: 333
|
| [47] | Danaee I, Jafarian M, Forouzandeh F, Gobal F, Mahjani M G. Int J Hydrogen Energy, 2009, 34: 859
|
| [48] | Subbaiah T, Mallick S C, Mishra K G, Sanjay K, Das R P. J Power Sources, 2002, 112: 562
|
| [49] | Nozad Golikand A, Shahrokhian S, Asgari M, Ghannadi Maragheh M, Irannejad L, Khanchi A. J Power Sources, 2005, 144: 21
|
| [50] | Spinner N, Mustain W E. Electrochim Acta, 2011, 56: 5656
|
| [51] | Singh R N, Sharma T, Singh A, Anindita, Mishra D, Tiwari S K. Electrochim Acta, 2008, 53: 2322
|
| [52] | Raoof J B, Ojani R, Hosseini S R. J Power Sources, 2011, 196: 1855
|
| [53] | Galus Z. Fundamentals of Electrochemical Analysis. New York: Ellis Horwood, 1976
|
| [54] | Jafarian M, Haghighatbin M A, Gobal F, Mahjani M G, Rayati S. J Electroanal Chem, 2011, 663: 14
|
| [55] | Ojani R, Raoof J B, Fathi S. J Solid State Electrochem, 2009, 13: 927
|
| [56] | Ojani R, Raoof J B, Hosseini Zavvarmahalleh S R. Electrochim Acta, 2008, 53: 2402
|
| [57] | Danaee I, Jafarian M, Mirzapoor A, Gobal F, Mahjani M G. Electrochim Acta, 2010, 55: 209
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
