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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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铑-ImiFerroPhos配合物对β-取代-α,β-不饱和磷酸酯的不对称氢化
DOI: 10.1016/S1872-2067(12)60742-6, PP. 227-231
Keywords: β-取代-α,β-不饱和磷酸酯,不对称催化氢化,ImiFerroPhos配体,铑(Ⅱ)配合物,手性β-取代烷基磷酸酯
Abstract:
？将手性二茂铁双膦配体ImiFerroPhos应用到β-取代-α，β-不饱和磷酸酯的不对称氢化反应中，在温和的反应条件下，以高收率及较高对映选择性合成了一系列β-取代的手性磷酸酯，最高获得了92%的ee值.
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