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催化学报  2014 

Silica-bondedpropylpiperazine-N-sulfamicacidasrecyclablesolidacidcatalystforpreparationof2-amino-3-cyano-4-aryl-5,10-dioxo-5,10-dihydro-4H-benzo[g]chromenesandhydroxy-substitutednaphthalene-1,4-dionederivatives

DOI: 10.1016/S1872-2067(12)60761-X, PP. 242-246

Keywords: Silica-bondedpropylpiperazine-N-sulfamicacid,Aldehyde,Malononitrile,Amine,Solvent-free,2-Hydroxynaphthalene-1,4-dione

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Abstract:

?Anefficientmethodforthesynthesisof2-amino-3-cyano-4-aryl-5,10-dioxo-5,10-dihydro-4H-benzo[g]chromenesandhydroxy-substitutednaphthalene-1,4-dionederivatives,usingsilica-bondedpropylpiperazine-N-sulfamicacidasasolidacid,green,heterogeneouscatalyst,underambientandsolvent-freeconditions,isdescribed.Asimpleprocedure,highyields,shortreactiontime,safety,andreusabilityofthecatalystareadvantagesoftheseprotocols.

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