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催化学报 2006
氧化锰八面体分子筛纳米棒的合成及其催化甲醛低温氧化性能, PP. 97-99 Abstract: ？Uniformmanganeseoxideoctahedralmolecularsieve(OMS-2)nanorodsweresynthesizedbyaddingasmallquantityofK2S2O8tothesolutioncontainingMnSO4·H2OandKMnO4,andusedforcompleteoxidationofformaldehyde.AccordingtotheresultsofN2adsorptionandX-raydiffraction,thematerialisamanganeseoxideoctahedralmolecularsievewiththecryptomelanetypestructure.TEMobservationshowsthatthediametersofthenanorodsrangefrom15to25nm,andthelengthsare300～400nm.CompleteconversionofHCHOtoCO2andH2Ocanbeachievedat353KoverOMS-2,andthesameconversionisobtainedat373KontheMnOxpowderunderthesameconditions,whichdemonstratesthatthecatalyticactivityiscloselyrelatedtothemorphologyofthecatalysts.
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