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催化学报 2010
非晶态介孔FeAlP催化剂用于合成1,5-苯二氮类化合物DOI: 10.1016/S1872-2067(10)60120-9, PP. 1321-1327 Keywords: benzodiazepine,amorphousmetalaluminophosphate,mesoporousironaluminophosphate,o-phenylenediamine,ketone,solventfreesynthesis Abstract: ？Asimpleandversatilemethodforthesynthesisof1,5-benzodiazepinesfromo-phenylenediamineandketonesinthepresenceofsolventsandundersolvent-freeconditionsthatusedanamorphousmesoporousironaluminophosphateascatalystwasdeveloped.Highyieldswithexcellentselectivitywereobtainedwithawidevarietyofketonesundermildreactionconditions.Thecatalysthadtheadvantagesofeaseofpreparation,easeofhandling,simplerecovery,reusability,nontoxicity,andbeinginexpensive.
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