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催化学报  2010 

碱性溶液中分子氧在多晶银上的多步还原

, PP. 541-546

Keywords: silver,oxygenreduction,cyclicvoltammetry,electrochemicalimpedancespectroscopy

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Abstract:

?Oxygenreductiononapolycrystallinesilverelectrodewasstudiedbycyclicvoltammetryandelectrochemicalimpedancespectroscopy.Thereactionoccurredbyatwo-electronpathway.Thestepsinthemechanismwereobservedinthecyclicvoltammogramsrecordedwithdifferentscanrates.Theintermediatesformedinthestepsweredetectedbyelectrochemicalimpedancespectroscopy.

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