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OALib Journal期刊
ISSN: 2333-9721
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手性磷酸催化芳香胺与硝基烯烃的不对称加成反应
DOI: ChiralPhosphoricAcidCatalyzedEnantioselectiveAza-Michael, PP. 1573-1576
Keywords: 手性磷酸,芳香胺,硝基烯烃,氮杂迈克尔加成
Abstract:
？以轴手性联萘酚为原料,合成了一系列手性磷酸催化剂,并首次将其应用于催化芳香胺和硝基烯烃的不对称氮杂迈克尔加成反应中,产物β-硝基胺的产率和对映选择性分别达65%~95%和16%~70%.
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