|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
聚乙二醇-水介质中水溶性膦稳定的钌催化芳香酮的不对称加氢反应
DOI: 10.3724/SP.J.1088.2011.10434, PP. 1490-1495
Keywords: 水溶性膦稳定的钌,芳香酮,不对称加氢,芳香仲醇,聚乙二醇-水
Abstract:
？在聚乙二醇-400-水介质中,以(1S,2S)-1,2-二苯基乙二胺的磺酸钠盐为手性修饰剂,考察了水溶性三(间-磺酸钠苯基)膦稳定的Ru催化苯乙酮及其衍生物的不对称加氢反应.结果表明,该催化剂体系具有良好的催化活性和对映选择性.在优化反应条件下,苯乙酮转化率和对映选择性分别为100%和84.9%.经正己烷萃取后,催化剂即可从产物中分离出来,并可重复使用多次.
| [1] | hkuma T, Koizumi M, Doucet H, Pham T, Kozawa M, Murata K, Katayama E, Yokozawa T, Ikariya T, Noyori R. J Am Chem Soc, 1998, 120: 13529
|
| [2] | hkuma T, Ishii D, Takeno H, Noyori R. J Am Chem Soc, 2000, 122: 6510
|
| [3] | hkuma T, Koizumi M, Muniz K, Hilt G, Kabuto C, Noyori R. J Am Chem Soc, 2002, 124: 6508
|
| [4] | go H L, Hu A, Lin W. Tetrahedron Lett, 2005, 46: 595
|
| [5] | rown R A, Pollet P, Mckoon E, Eckert C A, Liotta C L, Jessop P G. J Am Chem Soc, 2001, 123: 1254
|
| [6] | Nasar K, Fache F, Lemaire M, Draye M, Béziat J C, Besson M, Galez P. J Mol Catal, 1994, 87: 107
|
| [7] | BKnnemann H, Braun G A. Chem Eur J, 1997, 3: 1200
|
| [8] | Zuo X, Liu H, Guo D, Yang X. Tetrahedron, 1999, 55: 7787
|
| [9] | Astruc D, Lu F, Aranzaes J R. Angew Chem, Int Ed, 2005, 44: 7852
|
| [10] | 王金波, 明方永, 蒋维东, 樊光银, 刘德蓉, 陈华, 李贤均. 物理化学学报 (Wang J B, Ming F Y, Jiang W D, Fan G Y, Liu D R, Chen H, Li X J. Acta Phys-Chim Sin), 2007, 23: 1381
|
| [11] | 刘德蓉, 熊伟, 杨朝芬, 王金波, 陈华, 李瑞祥, 李贤均. 物理化学学报 (Liu D R, Xiong W, Yang Ch F, Wang J B, Chen H, Li R X, Li X J. Acta Phys-Chim Sin), 2007, 23: 479
|
| [12] | 姜和, 王金波, 熊伟, 贾云, 秦瑞香, 刘德蓉, 陈华. 物理化学学报 (Jiang H, Wang J B, Xiong W, Jia Y, Qin R X, Liu D R, Chen H. Acta Phys-Chim Sin), 2010, 26: 675
|
| [13] | 王金波, 秦瑞香, 熊伟, 贾云, 刘德蓉, 陈华. 催化学报 (Wang J B, Qin R X, Xiong W, Jia Y, Liu D R, Chen H. Chin J Catal), 2010, 31: 273
|
| [14] | Wang J B, Qin R X, Fu H Y, Chen J, Feng J, Chen H, Li X J. Tetrahedron: Asymmetry, 2007, 18: 847
|
| [15] | Wang J B, Feng J, Qin R X, Fu H Y, Yuan M L, Chen H, Li X J. Tetrahedron: Asymmetry, 2007, 18: 1643
|
| [16] | Andrade C K Z, Alves L M. Curr Org Chem, 2005, 9: 195
|
| [17] | Chen J, Spear S K, Hunddleston J G, Rogers R D. Green Chem, 2005, 7: 64
|
| [18] | Reetz M T, Wiesenhofer W. Chem Commun, 2004: 2750
|
| [19] | Chandrasekhar S, Narsihmulu C, Reddy N R, Sultana S S. Tetrahedron Lett, 2004, 45: 4581
|
| [20] | Xu L J, Lam K H, Ji J X, Wu J, Fan Q H, Lo W H, Chan A S C. Chem Commun, 2005: 1390
|
| [21] | Zhou H F, Fan Q H, Tang W J, Xu L J, He Y M, Deng G J, Zhao L W, Gu L Q, Chan A S C. Adv Synth Catal, 2006, 348: 2172
|
| [22] | Liu D R, Xiong W, Fan G Y, Chen H, Li R X, Li X J. Appl Catal A, 2008, 339: 93
|
| [23] | u L. Chem Rev, 1998, 98: 2405
|
| [24] | an Q H, Li Y M, Chan A S C. Chem Rev, 2002, 102: 3385
|
| [25] | uernik S, Wolfson A, Herskowitz M, Greenspoon N, Geresh S. Chem Commun, 2001: 2314
|
| [26] | hu Y H, Carpenter K, Bun C C, Bahnmueller S, Chan P, Srid V S, Kee L W, Hawthorne M F. Angew Chem, Int Ed, 2003, 42: 3792
|
| [27] | Ngo H L, Hu A, Lin W. Chem Commun, 2003: 1912
|
| [28] | Hu A, Ngo H L, Lin W. Angew Chem, Int Ed, 2004, 43: 2501
|
| [29] | Lam K H, Xu L J, Feng L C, Ruan J W, Fan Q H, Chan A S C. Can J Chem, 2005, 83: 903
|
| [30] | Studer M, Blaser H U, Exner C. Adv Synth Catal, 2003, 345: 45
|
| [31] | Tamura M, Fujihara H. J Am Chem Soc, 2003, 125: 15742
|
| [32] | Jansat S, Gomez M, Philippot K, Muller G, Guiu E, Claver C, Castillon S, Chaudret B. J Am Chem Soc, 2004, 126: 1592
|
| [33] | Tang B, Xiong W, Liu D R, Jia Y, Wang J B, Chen H, Li X J. Tetrahedron: Asymmetry, 2008, 19: 1397
|
| [34] | Zhou H F, Fan Q H, Huang Y Y, Wu L, He Y M, Tang W J, Gu L Q, Chan A S C. J Mol Catal A, 2007, 275: 47
|
| [35] | Zhou Z Q, Sun Y. React Kinet Mech Catal, 2010, 99: 391
|
| [36] | 陈华, 刘海超, 黎耀忠, 程溥明, 李贤均. 分子催化 (Chen H, Liu H Ch, Li Y Zh, Chen F M, Li X J. J Mol Catal (China)), 1994, 8:124
|
| [37] | Thorpe T, Brown S M, Crosby J, Fitzjohn S, Muxworthy J P, Williams J M. Tetrahedron Lett, 2000, 41: 4503
|
| [38] | Ma Y P, Liu H, Chen L, Cui X, Zhu J, Deng J G. Org Lett, 2003, 5: 2103
|
| [39] | Pugin B, Studer M, Kuesters E, Sedelmeier G, Feng X. Adv Synth Catal, 2004, 346: 1481
|
| [40] | Laghmari M, Sinou D. J Mol Catal, 1991, 66: L15
|
| [41] | Sandoval C A, Ohkuma T, Munlz K, Noyori R. J Am Chem Soc, 2003, 125: 13490
|
| [42] | 熊伟, 杨朝芬, 袁茂林, 陈华, 李贤均. 催化学报 (Xiong W, Yang Ch F, Yuan M L, Chen H, Li X J. Chin J Catal), 2005, 26: 1093
|
| [43] | Xiong W, Lin Q, Ma H X, Zheng H J, Chen H, Li X J. Tet-rahedron: Asymmetry, 2005, 16: 1959
|
| [44] | Noyori R, Ohkuma T. Angew Chem, Int Ed, 2001, 40: 40 3.0.CO;2-5 target="_blank">
|
| [45] | Kamaluddin A R, Faatz M, Alan A J, Morris R H. J Am Chem Soc, 2001, 123: 7473
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
