|
OALib Journal期刊
ISSN: 2333-9721
费用：99美元
|
|
|
|
碘化亚铜/亚磷酸三乙酯催化碘代芳烃和末端炔烃的偶联反应
DOI: 10.3724/SP.J.1088.2011.10311, PP. 1376-1379
Keywords: 碘化亚铜,亚磷酸三乙酯,碘代芳烃,末端炔烃,偶联反应
Abstract:
？以廉价的亚磷酸三乙酯为配体,首次用于Cu催化的碘代芳烃和末端炔烃的偶联反应,考察了不同Cu盐、金属纯度、碱和催化剂用量等条件对反应性能的影响.结果表明,当以高纯度的CuI(99.999%)为铜源,催化剂用量为5mol%时,在KOH作用下,该催化体系成功催化了一系列碘代芳烃和末端炔烃的反应,表现出良好的催化活性,此外,该催化体系还可用于2-苯基苯并呋喃的合成,为该类化合物的合成提供了一条较为经济的途径.
| [1] | hinchilla R, Nájera C. Chem Rev, 2007, 107: 874
|
| [2] | 维, 刘磊, 郭庆祥. 有机化学 (Deng W, Liu L, Guo Q X. Chin J Org Chem), 2004, 24: 150
|
| [3] | tephens R D, Castro C E. J Org Chem, 1963, 28: 3313
|
| [4] | kuro K, Furuune M, Enna M, Miura M, Nonura M. J Org Chem, 1993, 58: 4716
|
| [5] | eng C L, Xie Y X, Yin D L, Li J H. Synthesis, 2006, 20: 3370
|
| [6] | i J H, Li J L, Wang D P, Pi S F, Xie Y X, Zhang M B, Hu X C. J Org Chem, 2006, 72: 2053
|
| [7] | ang Y F, Deng W, Liu L, Guo Q X. Chin Chem Lett, 2005, 16: 1197
|
| [8] | ie Y X, Deng C L, Pi S F, Li J H, Yin D L. Chin J Chem, 2006, 24: 1290
|
| [9] | ang B X, Wang F, Li J H, Xie Y X, Zhang M B. J Org Chem, 2007, 72: 6294
|
| [10] | Guan J T, Yu G A, Chen L, Weng T Q, Yuan J J, Liu S H. Appl Organomet Chem, 2009, 23: 75
|
| [11] | Lin C H, Wang Y J, Lee C F. Eur J Org Chem, 2010: 4368
|
| [12] | Wu M Y, Mao J C, Guo J, Ji S J. Eur J Org Chem, 2008: 4050
|
| [13] | Ma D W, Liu F. Chem Commun, 2004: 1934
|
| [14] | Liu F, Ma D W. J Org Chem, 2007, 72: 4844
|
| [15] | Mao J, Guo J, Ji S J. J Mol Catal A, 2008, 284: 85
|
| [16] | Klapars A, Huang X H, Buchwald S L. J Am Chem Soc, 2002, 124: 7421
|
| [17] | Gonda Z, Tolnai G L, Novák Z. Chem Eur J, 2010, 16: 11822
|
| [18] | Lauterbach T, Livendahl M, Rosellón A, Esplnet P, Echavarren A M. Org Lett, 2010, 12: 3006
|
| [19] | Bates C G, Saejueng P, Murphy J M, Venkataraman D. Org Lett, 2002, 4: 4727
|
| [20] | Monnier F, Turtaut F, Duroure L, Taillefer M. Org Lett, 2008, 10: 3203
|
Full-Text
|
|
Contact Us
service@oalib.com QQ:3279437679 
WhatsApp +8615387084133
|
|
