OALib Journal期刊
ISSN: 2333-9721
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Silica-BondedN-PropylDiethylenetriamineSulfamicAcidasaRecyclableSolidAcidCatalystfortheSynthesisofα-Aminonitriles
DOI: 10.1016/S1872-2067(11)60383-5, PP. 1095-1100
Keywords: silica-bondedN-propyldiethylenetriaminesulfamicacid,α-aminonitrile,solidacid,aldehyde,heterogeneouscatalyst
Abstract:
?Silica-bondedN-propyldiethylenetriaminesulfamicacid(SBPDSA)isemployedasarecyclablecatalysttosynthesizeα-aminonitriles.Thesesynthesesinvolvedone-potcondensationofanaldehyde,anamine,andtrimethylsilylcyanideundermildreactionconditionsatroomtemperature.SBPDSAwasrecycledseventimesinthecondensationofbenzaldehyde,aniline,andtrimethylsilylcyanidewithoutreductionofitscatalyticactivity.
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