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OALib Journal期刊
ISSN: 2333-9721
费用：99美元
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活化温度对CuBTC催化CO氧化反应性能的影响
DOI: 10.1016/S1872-2067(11)60389-6, PP. 986-992
Keywords: 金属有机骨架材料,铜均苯三酸,一氧化碳,活化条件,气固催化
Abstract:
？考察了金属有机骨架材料CuBTC(BTC为均苯三酸)催化CO氧化的反应性能,发现CuBTC对CO氧化反应表现出良好的催化活性,且CuBTC样品的活化温度对其催化活性的影响很大.原位漫反射红外光谱、粉末X射线衍射、扫描电镜、热重分析和差示扫描量热结果表明,CO在CuBTC骨架中不饱和金属位点上的配位是加速CO氧化的主要原因,且这种不饱和金属位点越多,其催化活性越高.
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