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草业学报  2013 

玉簪属植物花瓣中类黄酮化合物价值评价

, PP. 234-244

Keywords: 玉簪,类黄酮,高效液相色谱,电喷雾离子化-多级质谱

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Abstract:

为拓宽玉簪属植物除园林方面的应用,本研究以玉簪属5个野生种和85个栽培品种的花瓣为材料,利用高效液相色谱(HPLC-DAD)技术,建立了定性定量分析玉簪花中类黄酮化合物的HPLC方法,可作为玉簪花药材的质量控制方法。同时结合质谱(MSn)技术,鉴定了玉簪花瓣中17种类黄酮化合物的化学结构,分别为:山奈酚3,7-二葡萄糖苷、山奈酚3-葡萄糖-7-芸香糖苷、异鼠李素3,4-二葡萄糖苷、山奈酚3-奎尼酰葡萄糖苷、山奈酚3-芥子酰葡萄糖苷、山奈酚3-抗坏血酰葡萄糖苷、山奈酚7-新橙皮糖苷、山奈酚3,7-二己糖苷、山奈酚3-葡萄糖-7-鼠李糖苷、木犀草素7-新橙皮糖苷、槲皮素3-葡萄糖苷、槲皮素3-葡糖苷酸、槲皮素3-刺槐二糖苷、山奈酚3-葡萄糖苷、山奈酚3-葡糖苷酸、山奈酚3-戊糖苷和山奈酚7-葡萄糖苷。并比较了90种玉簪花中类黄酮化合物成分与含量的差异性,筛选出类黄酮化合物含量较高的种类。

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