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Sasobit改性沥青的结构与性能研究

, PP. 18-25

Keywords: 道路工程,Sasobit改性沥青,试验研究,微观结构,化学反应

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Abstract:

?在Pen60/80基质沥青中加入不同含量的Sasobit,应用常规的沥青性能试验(针入度试验、粘度试验、组分试验等)测试Sasobit改性沥青分别在15℃,25℃,30℃的针入度和软化点,以及60℃,120℃,135℃的粘度和组分等性能指标;通过旋转薄膜加热试验(RTFOT)和压力老化容器(PAV)试验模拟沥青的短期老化和长期老化,评价Sasobit改性沥青的耐久性。同时,利用凝胶色谱仪(GPC)和红外光谱仪(IR)测试Sasobit改性沥青的分子量分布、官能团变化等微观性能,分析Sasobit对沥青宏观性能、官能团以及分子量等微观性能的影响,定性地建立Sasobit改性沥青微观性能与宏观性能之间的关系,从微观角度分析Sasobit改性沥青的性能变化规律。结果表明:在沥青中加入Sasobit后,Sasobit与沥青中的—OH和C—H发生了化学反应,这些化学反应导致沥青中出现了新的芳香族C—O键,并使得Sasobit的长链烷基与沥青中的沥青蜡发生了共晶,因而改变了沥青的晶体结构、组分比例以及胶体结构,使沥青的性能有了明显的改变,提高了沥青的高温性能,降低了沥青的低温性能;这一点与在沥青混合料中加入Sasobit后所表现出来的路用性能正好吻合。

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