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聚苯胺/石墨烯水性涂料的制备及其防腐性能研究

DOI: 10.13334/j.0258-8013.pcsee.2015.S.023, PP. 170-176

Keywords: 聚苯胺/石墨烯,水性涂料,防腐性能,屏障性能

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Abstract:

为了提高聚苯胺水性涂料的防腐性能,利用苯胺和氧化石墨烯(GO)作为原料,采用原位聚合-还原法制备聚苯胺/石墨烯(PAG)复合材料,再利用PAG与水性环氧树脂共混制备聚苯胺/石墨烯水性环氧防腐涂料。通过傅里叶红外光谱(FTIR)、X射线衍射(XRD)、扫描电镜(SEM)分析PAG的结构和微观形貌,利用动电位极化曲线和电化学交流阻抗谱(EIS)分析PAG水性涂层的防腐性能。结果表明,PAG保持了石墨烯的基本形貌,聚苯胺颗粒均匀地分散在石墨烯表面和片层间,形成片状插层结构;当PAG浸泡在3.5%NaCl溶液中,PAG涂层的阻抗值最大,腐蚀电流密度为24.30μA/cm2,PAG对碳钢的保护度达到94.24%,优于PANI水性涂料的防腐性能(PANI水性涂层涂覆碳钢的腐蚀电流密度和保护度分别为43.17μA/cm2和88.97%);与PANI水性涂层和水性环氧树脂涂层相比,PAG水性涂层对O2和H2O分子具有更好的屏障性能。

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