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分级富氧燃烧控制NOx的一维模型和试验研究

DOI: 10.13334/j.0258-8013.pcsee.2014.26.003, PP. 4462-4468

Keywords: 分级富氧燃烧,NO,沉降炉,一维模型,Cantera软件

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Abstract:

为研究富氧燃烧过程中的NOx生成与控制,在一维沉降炉上进行了煤的分级富氧燃烧试验,并利用Matlab和Cantera软件建立了一维沉降炉反应模型并进行分析。试验温度1100~1200℃,给粉量21.1~32.3g/h。试验和模拟结果表明:富氧燃烧时不采用烟气再循环的方法时NOx生成量也可比空气下燃烧时低。在未分级条件下,富氧燃烧时的NOx排放量是空气工况的77%。通过推迟二次风后移、缩小一次风风率等手段延长一次风在还原区的停留时间,可降低富氧燃烧时的NOx生成量。高浓度CO2和焦炭的气化反应有助于强化还原区的还原性气氛,促进NO在焦炭表面的还原,促进焦炭N向N2的转化,抑制焦炭NOx的生成。一维模型模拟结果与试验吻合。

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