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焚烧过程中铅在PM10中的分布特性及以高岭土为吸附剂炉内捕集铅的研究

DOI: 10.13334/j.0258-8013.pcsee.2014.14.001, PP. 2221-2227

Keywords: 流化床焚烧炉,,高岭土,共晶融化,捕集

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Abstract:

在流化床焚烧炉内考察了铅(Pb)在PM10中的分布特性,并将高岭土作为吸附剂进行炉内捕集Pb的研究。用低压冲击器、原子吸收分光光度计和扫描电镜/能谱仪对焚烧烟气中Pb的粒径-浓度分布、飞灰颗粒表面形貌和表面元素分布进行了分析。结果表明,高岭土表面与Pb反应会引发共晶融化,过量共晶融化使高岭土孔隙坍塌成球形颗粒,其融化表面可黏附已生成的亚微米铅颗粒;PM10中90%以上的Pb富集在亚微米颗粒物中,仅有少量Pb存在于粗颗粒物中,而且随着温度升高亚微米Pb的浓度逐渐增加;高岭土可以促进烟气中Pb从细颗粒物中迁移到粗颗粒物中,从而减少亚微米Pb排放;随高岭土添加量增,高岭土对Pb的捕集效率逐渐增加,最佳捕集温度为950℃,最高捕集效率达80%。

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