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科学通报  2011 

超支化聚合物研究最新进展

DOI: 10.1360/972010-2339, PP. 1683-1695

Keywords: 超支化聚合物,共轭聚合物,结构,合成,性质,应用

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Abstract:

超支化聚合物由于具有高度支化的三维球状立体结构和众多的末端基团,显示出与相应线型分子截然不同的性质,如低黏度、良好的溶解性和大量可修饰的末端官能团等,具有广泛的应用前景,而且合成相对简单、成本低,因此成为近年来聚合物科学领域的研究热点.本文主要就超支化聚合物的结构、合成、性质和应用,从传统结构和含有大π共轭结构的新型超支化聚合物两个角度比较全面地总结了这一领域在基础理论和应用研究方面的发展概况和最新进展;着重介绍了超支化聚合物的结构、性质与其在新型功能材料如纳米材料、药物缓释剂、电致发光材料、传感材料等方面应用的内在关系,并进一步提出了该领域的研究前景及尚待解决的问题.

References

[1]  2 Flory P J. Molecular size distribution in three dimensionalpolymers. VI. Branched polymers containing A-R-Bf-1type units. J Am ChemSoc, 1952, 74: 2718-2723
[2]  4 Kim Y H, Webster O W. Hyperbranched polyphenylenes. Polym Prepr, 1988, 29: 310-311
[3]  7 Hawker C J, Lee R, FréEchet J M J. One-step synthesis of hyperbranched dendritic polyesters. J Am Chem Soc, 1991, 113: 4583-4588??
[4]  8 Shi J B, Mahtab F, Liu J Z, et al. Ferrocene-functionalized hyperbranched polyphenylenes: Synthesis, redox activity, light refraction,transition-metal complexation, and precursors to magnetic ceramics. Macromolecules, 2010, 43: 680-690??
[5]  10 彭汉, 董宇平, 贾德民, 等. 易加工、热稳定和高效发光的超支化聚苯的合成. 科学通报, 2004, 49: 2617-2619
[6]  11 Uhrich K E, Hawker C J, FréChet J M J. One-pot synthesis of hyperbranched polyethers. Macromolecules, 1992, 25: 4583-4587??
[7]  12 Fan Z R, Lederer A, Voit B. Synthesis and characterization of A(2)+B-3-type hyperbranched aromatic polyesters with phenolic end groups.Polymer, 2009, 50: 3431-3439??
[8]  13 Kishore K, Prathab R B, Aminabhavi T M. Hyperbranched polyesters: Synthesis, characterization, and molecular simulations. J PhysChem B, 2007, 111: 8801-8811
[9]  15 Kim Y H. Lyotropic liquid-crystalline hyperbrached aromatic polyamides. J Am Chem Soc, 1992, 114: 4947-4948??
[10]  16 Uhrich K E, Boegeman S, FréEchet J M J. Solid-phase synthesis of dendritic polyamides. Polym Bull, 1991, 25: 551-558??
[11]  20 Mathias L J , Carothers T W. Hyperbranched poly(siloxysilanes). J Am Chem Soc, 1991, 113: 4043-4044??
[12]  23 Ma Z, Lu S, Huang W. Synthesis, characterization, and energy transfer properties of benzothiadiazole-based hyperbranched polyfluorenes.Polymer, 2006, 47: 7382-7390??
[13]  24 Xin Y, Wen G A, Zeng W J, et al. Hyperbranched oxadiazole-containing polyfluorenes: Toward stable blue light PLEDs. Macromolecules,2005, 38: 6755-6758??
[14]  31 Hong H Y, Mai Y Y, Zhou Y F, et al. Synthesis and supramolecular self-assembly of thermosensitive amphiphilic star copolymers basedon a hyperbranched polyether core. J Polym Sci, Part A: Polym Chem, 2008, 46: 668-681??
[15]  33 Liu G T, Zhao M S. Isothermal crystallization kinetics of AB3 hyperbranched polymer (HBP)/polypropylene (PP) blends. Polym Bull,2009, 63: 565-573??
[16]  35 Wang L, He X H. Conformation of nonideal hyperbranched polymer in AB(n) (n=2, 4) type polymerization. J Poly Sci Part B: Polym Phys,2010, 48: 610-616
[17]  37 Schmaljohann D, Komber H, Barratt J G, et al. Kinetics of nonideal hyperbranched polymerizations. 2. Kinetic analysis of thepolycondensation of 3,5-bis(trimethylsiloxy)benzoyl chloride using NMR spectroscopy. Macromolecules, 2003, 36: 97-108
[18]  39 Thompson D S, Markoski L J, Moore J S. Rapid synthesis of hyperbranched aromatic polyetherimides. Macromolecules, 1999, 32:4764-4768??
[19]  41 FréChet J M J, Henmi M, Gitsov I, et al. Self-condensing vinyl polymerization—An approach yo dendritic materials. Science, 1995, 269:1080-1083??
[20]  49 Liu X H, Dong Z M, Tang X L, et al. Synthesis and characterization of hyperbranched polymers via Cp2TiCl-catalyzed self-condensingvinyl polymerization using glycidyl methacrylate as inimer. Polymer, 2010, 51: 854-859??
[21]  52 Bednarek M, Pluta M. Oligomeric branched polyethers with multiple hydroxyl groups by cationic ring-opening polymerization forinorganic surface modification. Macromol Symp, 2010, 287: 119-126??
[22]  53 Rahm M, Westlund R, Eldsater C, et al. Tri-block copolymers of polyethylene glycol and hyperbranched poly-3-ethyl-3-(hydroxymethyl)oxetane through cationic ring opening polymerization. J Polym Sci, Part A: Polym Chem, 2009, 47: 6191-6200??
[23]  54 Parzuchowski P G, Grabowska M, Jaroch M, et al. Synthesis and characterization of hyperbranched polyesters from glycerol-based AB2Monomer. J Polym Sci, Part A: Polym Chem, 2009, 47: 3860-3868??
[24]  55 Sunder A, Hanselmann R, Frey H, et al. Controlled synthesis of hyperbranched polyglycerols by ring-opening multibranching polymerization.Macromolecules, 1999, 32: 4240-4246??
[25]  58 Emrick T, Chang H T, Freechet J M J. An A2+B3 approach to hyperbranched aliphatic polyethers containing chain end epoxy substituents.Macromolecules, 1999, 32: 6380-6382??
[26]  59 Monticelli O, Mariani A, Voit B, et al. Hyperbranched aramids by the A(2)+B-3 Versus AB(2) approach: Influence of the reactionconditions on structural development. High Perform Polym, 2001, 13: 45-59??
[27]  60 Xie J D, Hu L H, Shi W F, et al. Synthesis and characterization of hyperbranched polytriazole via an ‘A2+ B3’ approach based on clickchemistry. Polym Int, 2008, 57: 965-974??
[28]  65 Zhu X, Jaumann M, Peter K. One-pot synthesis of hyperbranched polyethoxysiloxanes. Macromolecules, 2006, 39: 1701-1708??
[29]  71 Stijn F M van Dongen, Ruud J R W, Jan C M. Biohybrid polymer capsules. Chem Rev, 2009, 109: 6212-6274??
[30]  73 Prabaharan M, Grailer J J, Pilla S, et al. Amphiphilic multi-arm block copolymer based on hyperbranched polyester, poly(L-lactide) andpoly(ethylene glycol) as a drug delivery carrier. Macromol Biosci, 2009, 9: 515-524??
[31]  74 Burn P L, Lo S C, Samuel D W. The development of light-emitting dendrimers for displays. Adv Mater, 2007, 19: 1675-1688??
[32]  75 He Q Y, Lai W Y, Ma Z, et al. Novel blue light-emitting hyperbranched polyfluorenes incorporating carbazole kinked structure. EurPolym J, 2008, 44: 3169-3176
[33]  79 Li M H, Liu Y B, Wang S. Water-soluble dendritic-conjugated polyfluorenes: Synthesis, characterization, and interactions with DNA. JPolym Sci, Part A: Polym Chem, 2008, 46: 7462-7472??
[34]  80 Ekinci E, Bilgeemre F, K?ytepe S, et al. Preparation, characterization and H2O2 selectivity of hyperbranched polyimides containingtriazine. J Polym Res, 2005, 12: 205-210
[35]  81 Koytepe S, Pasahan A, Ekinci E, et al. Synthesis, characterization and H2O2-sensing properties of pyrimidine-based hyperbranchedpolyimides. Eur Polym J, 2005, 41: 121-127
[36]  50 Suzuki M, Saegusa T. Multibranching polymerization: Palladium-catalyzed ring-opening polymerization of cyclic carbamate to producehyperbranched dendritic polyamine. Macromolecules, 1992, 25: 7071-7072??
[37]  51 Suzuki M, Yoshida S, Shiraga K, et al. New ring-opening polymerization via a pi-allylpalladium complex. 5. Multibranchingpolymerization of cyclic carbamate to produce hyperbranched dendritic polyamine. Macromolecules, 1998, 31: 1716-1719
[38]  56 Wilms D, Stiriba S E, Frey H. Hyperbranched Polyglycerols: From the controlled synthesis of biocompatible polyether polyols tomultipurpose applications. Accounts Chem Res, 2010, 43: 129-141??
[39]  57 Jikei M, Chon S H, Kakimoto M, et al. Synthesis of hyperbranched aromatic polyamide from aromatic diamines and trimesic acid.Macromolecules,1999, 32: 2061-2064??
[40]  61 Bao B Q, Yuwen L H, Zhan X W, et al. Water-soluble hyperbranched polyelectrolytes with high fluorescence quantum yield: Facilesynthesis and selective chemosensor for Hg2+ and Cu2+ ions. J Polym Sci Part A: Polym Chem, 2010, 48: 3431-3439??
[41]  62 Yan D Y, Gao C. Hyperbranched polymers made from A(2) and BB ′(2) type monomers.1. Polyaddition of 1-(2-aminoethyl)piperazine todivinyl sulfone. Macromolecules, 2000, 33: 7693-7699
[42]  63 Froehling P, Brackman J. Properties and applications of poly(propylene imine) dendrimers and poly(esteramide) hyperbranched polymers.Macromol Symp, 2000, 151: 581-589??
[43]  64 Kim Y J, Kakimoto M, Kim S Y. Synthesis of hyperbranched poly(arylene ether) from monomer containing nitro group: Kineticallycontrolled growth of polymer chain through dynamic exchange of end functional groups. Macromolecules, 2006, 39: 7190-7192??
[44]  66 Wang D, Zheng Z, Hong C. Michael addition polymerizations of difunctional amines (AA′) and triacrylamides (B-3). J Polym Sci, Part A:Polym Chem, 2006, 44: 6226-6242??
[45]  67 Lin Y, Dong Z M, Li Y S. One-pot synthesis and characterization of hyperbranched poly(ester-amide)s from commercially availabledicarboxylic acids and multihydroxyl secondary amines. J Polym Sci, Part A: Polym Chem, 2008, 46: 5077-5092??
[46]  68 Lin Y, Gao J W, Li Y S, et al. Synthesis and characterization of hyperbranched poly(ether amide)s with thermoresponsive property andunexpected strong blue photoluminescence. Macromolecules, 2009, 42: 3237-3246??
[47]  69 Frechet J M J, Hawker C J. Hyperbranched polyphenylene and hyperbranched polyesters: New soluble, three-dimensional, reactivepolymers. React Funct Polym, 1995, 26: 127-136??
[48]  70 Kim Y H, Webster O W. Hyperbranched polyphenylenes. Macromolecules, 1992, 25: 5561-5572??
[49]  72 Xia W, Jiang G H, Chen W X. Synthesis and drug-release properties of hyperbranched polyesters grafted with biocompatible poly(ε-caprolactone). J Appl Polym Sci, 2008, 109: 2089-2094??
[50]  76 Guan R, Xu Y H, Ying L, et al. Novel green-light-emitting hyperbranched polymers with iridium complex as core and 3,6-carbazole-co-2,6-pyridine unit as branch. J Mater Chem, 2008, 19: 531-537
[51]  77 Zhao M Q, Sun L, Crooks R M. Preparation of Cu nanoclusters within dendrimer templates. J Am Chem Soc, 1998, 120: 4877-4878??
[52]  78 陈文求, 杨小进, 李全涛, 等. 超支化聚酰亚胺的改性研究. 化学进展, 2009, 21: 1560-1568
[53]  82 Thompson C H, Hu J, Kaganove S N, et al. Hydrogen-bond acidic hyperbranched polymers for surface acoustic wave (SAW) Sensors.Chem Mater, 2004, 16: 5357-5364??
[54]  1 Kienle R H, Hovey A G. The polyhydric alcohol-polybasic acid reaction. I. Glycerol-phthalic anhydride. J Am Chem Soc, 1929, 51:509-519??
[55]  3 Kim Y H, Webster O W. Water-soluble hyperbranched polyphenylene: A unimolecular micelle? J Am Chem Soc, 1990, 112: 4592-4593
[56]  5 Voit B, Lederer A. Hyperbranched and highly branched polymer architectures synthetic strategies and major characterization aspects.Chem Rev, 2009, 109: 5924-5973??
[57]  6 Gao C, Yan D Y. Hyperbranched polymers: From synthesis to applications. Prog Polym Sci, 2004, 29: 183-275??
[58]  9 Kushakova N S, Shapovalov A V, Rud D A, et al. Synthesis of hyperbranched polyphenylenes by suzuki reaction and their spectralcharacteristics. Polym Sci Ser B, 2008, 51: 409-415
[59]  14 Liou G S, Lin H Y, Yen H J. Synthesis and characterization of electroactive hyperbranched aromatic polyamides based on A B-typetriphenylamine moieties. J Mater Chem, 2009, 19: 7666-7673??
[60]  17 Sivakumar C, Nasar S A. Hydroxyl- and amine-terminated hyperbranched polyurethanes using AB2-type azide monomers: Synthesis,characterization, fluorescence, and charge-transfer complexation studies. J Polym Sci, PartA: Polym Chem, 2009, 47: 3337-3351??
[61]  18 Vanjinathan M, Shanavas A, Nasar A S. Synthesis and properties of hyperbranched polyurethanes, hyperbranched polyurethane copolymerswith and without ether and ester groups using blocked ssocyanate monomers. J Polym Sci, PartA: Polym Chem, 2007, 45: 3877-3893??
[62]  19 Yates C R, Hayes W. Synthesis and applications of hyperbranched polymers. Eur Pol J, 2004, 40: 1257-1281??
[63]  21 张璐, 封伟. 树枝状共轭聚合物研究. 化学进展, 2007, 19: 337-349
[64]  22 Zhao Q, Liu S J, Huang W. Polyfluorene-based blue-emitting materials. Macromol Chem Phys, 2009, 210: 1580-1590??
[65]  25 Wen G A, Xin Y, Peng B, et al. Hyperbranched triazine-containing polyfluorenes: Efficient blue emitters for polymer light-emitting diodes(PLEDs). Polymer, 2007, 48: 1824-1829??
[66]  26 Tang D F, Wen G A, Wei W, et al. Photocrosslinkable hyperbranched polyfluorenes containing oxadiazole: Synthesis, photophysics andelectroluminescence. Polym Int, 2008, 57: 1235-1241??
[67]  27 Tang D F, Wen G A, Qi X Y, et al. Spectrum-stable hyperbranched polyfluorene with photocrosslinkable group. Polymer, 2007, 48:4412-4418??
[68]  28 Zhu B, Han Y, Sun M H, et al. Water-soluble dendronized polyfluorenes with an extremely high quantum yield in water. Macromolecules,2007, 40: 4494-4450??
[69]  29 Yu M H, Liu L B, Wang S. Water-soluble dendritic-conjugated polyfluorenes: Synthesis, characterization, and interactions with DNA. JPolym Sci, PartA: Polym Chem, 2008, 46: 7462-7472??
[70]  30 Malenfant P R L, Fréchet J M J. Dendrimers as solubilizing groups for conducting polymers: Preparation and characterization ofpolythiophene functionalized exclusively with aliphatic ether convergent dendrons. Macromolecules, 2000, 33: 3634-3640??
[71]  32 Ohta Y, Fujii S, Yokoyama A, et al. Synthesis of well-defined hyperbranched polyamides by condensation polymerization of AB2monomer through changed substituent effects. Angew Chem Int Ed, 2009, 48: 5942-5945??
[72]  34 Ishida Y, Yokomachi K, Seino M, et al. Synthesis, end-functionalization and characterization of hyperbranched polysiloxysilanes fromAB(3) type monomer. Macromol Res, 2007, 15: 147-153
[73]  36 Miravet J F, Fréchet J M J. New hyperbranched poly(siloxysilanes): Variation of the branching pattern and end-functionalization.Macromolecules, 1998, 31: 3461-3468??
[74]  38 Komber H, Ziemer A, Voit B. Etherification as side reaction in the hyperbranched polycondensation of 2,2-bis(hydroxymethyl)propionicacid. Macromolecules, 2002, 35: 3514-3519
[75]  40 Hult A, Johansson M, Malmstroem E. Hyperbranched polymers. Adv Polym Sci, 1999, 143: 1-34??
[76]  42 Nuyken O, Gruber F, Pask S D, et al. The synthesis of alpha-tert-butyl-omega-[p-vinylphenyl]-terminated poly(2-methylpropene)macromonomers. Macromol Chem, 1993, 194: 3415-3432??
[77]  43 Peleshanko S, Gunawidjaja R, Petrash S, et al. Synthesis and interfacial behavior of amphiphilic hyperbranched polymers: Poly(ethyleneoxide)-polystyrene hyperbranches. Macromolecules, 2006, 39: 4756-4766??
[78]  44 Zou P, Yang L P, Pan C Y. One-pot synthesis of linear-hyperbranched diblock copolymers via self-condensing vinyl polymerization andring opening polymerization. J Polym Sci, Part A: Polym Chem, 2008, 46: 7628-7636??
[79]  45 Mei X, Liu A H, Cui J X, et al. Synthesis and characterization of branched mesogen-jacketed liquid crystal polymers based on2,5-bis[(4’-methoxyphenyl)oxycarbonyl]styrene and 4-chloromethylstyrene. Macromolecules, 2008, 41: 1264-1272
[80]  46 Tao L, Liu J Q, Tan B H, et al. RAFT Synthesis and DNA binding of biodegradable, hyperbranched poly(2-(dimethylamino)ethylmethacrylate. Macromolecules, 2009, 42: 4960-4962
[81]  47 Vogt A P, Sumerlin B S. Tuning the temperature response of branched poly(N-isopropylacrylamide) prepared by RAFT polymerization.Macromolecules, 2008, 41: 7368-7373??
[82]  48 Asandei A D, Moran I W. TiCp2Cl-catalyzed living radical polymerization of styrene initiated by oxirane radical ring opening. J AmChem Soc, 2004, 126: 15932-15933??

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