全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...
科学通报  2014 

苄基紫精混合卤代铅盐的合成、结构及电学性质

DOI: 10.1360/972013-869, PP. 1625-1630

Keywords: 混合卤代铅盐,结构,半导体,溶剂热合成,苄基紫精

Full-Text   Cite this paper   Add to My Lib

Abstract:

通过苯甲醇与4,4’-联吡啶,PbCl2,I2在乙腈和水的混合溶液中的溶剂热反应,得到新颖的具有碘离子和氯离子混合的苄基紫精卤代铅盐[(BV)2(Pb5I8Cl6)]n(1)(BV2+=苄基紫精或N,N’-二苄基-4,4’-联吡啶鎓).化合物1的阴离子结构可视为通过共享PbI3Cl3,PbI5Cl或PbI6八面体的边缘形成的一维[Pb5I8Cl6]n4n-链状结构,而BV2+二价阳离子可能是由苯甲醇中的C-O键断裂后与4,4’-联吡啶苄基化原位形成的.在293~443K的温度范围,化合物1的单晶电导率从1.54×10-6增加至2.11×10-5Sm-1,表明化合物1具有典型的半导体行为.

References

[1]  1 Mitzi D B, Feild C A, Harrison W T A, et al. Conducting tin halides with a layered organic-based perovskite structure. Nature, 1994, 369: 467-469
[2]  2 Kagan C R, Mitzi D B, Chondroudis K. Organic-inorganic hybrid materials as semiconducting channels in thin-film field-effect transistors. Science, 1999, 286: 945-947
[3]  3 Mitzi D B, Wang S, Field C A, et al. Conducting layered organic-inorganic halides containing <110>-oriented perovskite sheets. Science, 1995, 267: 1473-1476
[4]  5 Guloy A M, Tang Z J, Miranda P B, et al. A new luminescent organic-inorganic hybrid compound with large optical nonlinearity. Adv Mater, 2001, 13: 833-837
[5]  13 Chai W X, Wu L M, Li J Q, et al. Silver iodobismuthates: Syntheses, structures, properties, and theoretical studies of[Bi2Ag2I102-]n and[Bi4Ag2I162-]n. Inorg Chem, 2007, 46: 1042-1044
[6]  14 Chai W X, Wu L M, Li J Q, et al. A series of new copper iodobismuthates: Structural relationships, optical band gaps affected by dimensionality, and distinct thermal stabilities. Inorg Chem, 2007, 46: 8698-8704
[7]  15 Li J P, Li L H, Wu L M, et al. Synthesis, properties, and theoretical studies of new stepwise layered iodoplumbate:[Ni(opd)2(acn)n[Pb4I10]n. Inorg Chem, 2009, 48: 1260-1262
[8]  17 Oldag T, Aussieker T, Keller H L, et al. Solvothermale synthese und bestimmung der kristallstrukturen von AgBiI4 und Ag3BiI6. Z Anorg Allg Chem, 2005, 631: 677-682
[9]  19 Kitazawa N. Optical absorption and photoluminescence properties of Pb(I, Br)-based two-dimensional layered perovskite. Jpn J Appl Phys, 1997, 36: 2272-2276
[10]  21 Staulo G, Bellito C. (C6H5CH2NH3)2CrBr3.3I0.7: A new insulating ferromagnet with a curie temperature of 51 K. J Mater Chem, 1991, 1: 915-918
[11]  22 Chen Y, Wang Z O, Lang J P, et al. Unique assembly of low-dimensional viologen iodoplumbates and their improved semiconducting properties. Dalton Trans, 2010, 39: 9476-9479
[12]  23 Chen Y, Yang Z, Lang J P, et al. Iodine-induced solvothermal formation of viologen iodobismuthates. Eur J Inorg Chem, 2010, 33: 5326-5333
[13]  24 Chen Y, Yang Z, Lang J P, et al. Using alcohols as alkylation reagents for 4-cyanopyridinium and N, N'-dialkyl-4, 4'-bipyridinium and their one-dimensional iodoplumbates. CrystEngComm, 2011, 13: 243-250
[14]  25 CrystalClear Package. Version 1.3. Tokyo: Rigaku and MSC, 2001
[15]  26 CrystalStructure Package. Version 3.60. Tokyo: Rigaku and MSC, 2004
[16]  27 Nakamoto K. Infrared and Raman Spectra of Inorganic and Coordination Compounds. 4th ed. New York: Wiley, 1986
[17]  28 Billing D G, Lemmerer A. Synthesis and crystal structures of inorganic-organic hybrids incorporating an aromatic amine with a chiral functional group. CrystEngComm, 2006, 8: 686-695
[18]  29 Corradi A B, Ferrari A M, Righi L, et al. An additional structural and electrical study of polymeric haloplumbates(Ⅱ) with heterocyclic diprotonated amines. Inorg Chem, 2001, 40: 218-223
[19]  34 Heulings H R, Huang X Y, Li J, et al. Mn-substituted inorganic-organic hybrid materials based on ZnSe: Nanostructures that may lead to magnetic semiconductors with a strong quantum confinement effect. Nano Lett, 2001, 1: 521-525
[20]  37 Holstein T. Studies of polaron motion: Part Ⅱ. The "small" polaron. Ann Phys, 1959, 8: 343-389
[21]  4 Calabrese J, Jones M L, Harlow R L, et al. Preparation and characterization of layered lead halide compounds. J Am Chem Soc, 1991, 113: 2328-2330
[22]  6 Mitzi D B, Dimitrakopoulos C D, Rosner J, et al. Hybrid field-effect transistor based on a low-temperature melt-processed channel layer. Adv Mater, 2002, 14: 1772-1776
[23]  7 Castro-Castro L M, Guloy A M. Organic-based layered perovskites of mixed-valent gold(Ⅰ)/gold(Ⅲ) iodides. Angew Chem Int Ed, 2003, 42: 2771-2774
[24]  8 Mitzi D B. Solution-processed inorganic semiconductors. J Mater Chem, 2004, 14: 2355-2365
[25]  9 Takahashi Y, Obara R, Nakagawa K, et al. Tunable charge transport in soluble organic-inorganic hybrid semiconductors. Chem Mater, 2007, 19: 6312-6316
[26]  10 Bi W, Louvain N, Mercier N, et al. A switchable NLO organic-inorganic compound based on conformationally chiral disulfide molecules and Bi(Ⅲ)I5 iodobismuthate networks. Adv Mater, 2008, 20: 1013-1017
[27]  11 Bi W, Leblanc N, Mercier N, et al. Thermally induced Bi(Ⅲ) lone pair stereoactivity: Ferroelectric phase transition and semiconducting properties of (MV)BiBr5 (MV= methylviologen). Chem Mater, 2009, 21: 4099-4101
[28]  12 Fan L Q, Wu L M, Chen L. Syntheses, crystal structures, and properties of heterometallic iodoplumbates: Bicubane, ribbon, and chain configurations. Inorg Chem, 2006, 45: 3149-3151
[29]  16 Feldmann C. CuBi7I19(C4H8O3H)3(C4H8O3H2), a novel complex bismuth iodide containing one-dimensional[CuBi5I3- chains. Inorg Chem, 2001, 40: 818-819
[30]  18 Sourisseau S, Louvain N, Bi W, et al. Hybrid perovskite resulting from the solid-state reaction between the organic cations and perovskite layers of α1-(Br-(CH2)2-NH3)2PbI4. Inorg Chem, 2007, 46: 6148-6154
[31]  20 Kitazawa N. Excitons in two-dimensional layered perovskite compounds: (C6H5C2H4NH3)2Pb(Br, I)4 and (C6H5C2H4NH3)2Pb(Cl, Br)4. Mater Sci Eng, 1997, B49: 233-238
[32]  30 Wendlandt W W, Hecht H G. Reflectance Spectroscopy. New York: Interscience Publishers, 1966
[33]  31 Zhu X H, Wei Z R, Jin Y R, et al. Growth and characterization of a PbI2 single crystal used for gamma ray detectors. Cryst Res Technol, 2007, 42: 456-459
[34]  32 Cusack L, Marguerettaz X, Rao S N, et al. Heterosupramolecular chemistry: Self-assembly of an electron donor (TiO2 nanocrystallite)-acceptor (viologen) complex. Chem Mater, 1997, 9: 1765-1772
[35]  33 Huang X Y, Heulings H R, Le V, et al. Inorganic-organic hybrid composites containing MQ (Ⅱ-VI) slabs: A new class of nanostructures with strong quantum confinement and periodic arrangement. Chem Mater, 2001, 13: 3754-3759
[36]  35 Chen Y, Wang Z O, Lang J P, et al. Solvothermal stepwise formation of Cu/I/S-based semiconductors from a three-dimensional net to one-dimensional chains. Cryst Growth Des, 2009, 9: 4963-4968
[37]  36 Colinge J P, Colinge C A. Physics of Semiconductor Devices. Norwell, MA: Kluwer Academic Publishers, 2002
[38]  38 Horowitz G. Organic field-effect transistors. Adv Mater, 1998, 10: 365-377

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133