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科学通报  2015 

过渡金属催化的经C-H键活化/脱羧(磺)偶联反应进展

DOI: 10.1360/N972015-00144, PP. 2918-2926

Keywords: C-H键活化,C-C键生成,过渡金属催化,脱羧偶联,脱磺偶联

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Abstract:

过渡金属催化的C-H键活化和官能化(C-C偶联反应)是当前有机合成化学极具挑战性的研究课题之一.近年来探索过渡金属催化的脱羧和脱磺偶联反应引起了人们的极大关注,并取得了很好的研究结果.常用的过渡金属催化剂有钯(Pd)、铜(Cu)、银(Ag)、铑(Rh)、铁(Fe)等.本文综述了近几年过渡金属催化的经C-H键活化/脱羧和脱磺偶联反应研究进展.

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