全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...
科学通报  2011 

磁控溅射法制备氧化铜纳米线阵列薄膜及其气敏性质

DOI: 10.1360/972011-418, PP. 2383-2388

Keywords: 磁控溅射,CuO,纳米线,阵列薄膜,气敏性质

Full-Text   Cite this paper   Add to My Lib

Abstract:

通过磁控溅射法在掺氟二氧化锡导电玻璃(FTO)衬底上溅射金属铜薄膜,所制备的Cu薄膜在管式炉中退火氧化生长得到CuO纳米线阵列薄膜.用X射线衍射仪(XRD)、扫描电子显微镜(SEM)、高分辨透射电子显微镜(HRTEM)对其形貌和结构进行了表征,并研究了这种通过磁控溅射得到的CuO纳米线阵列薄膜对CO和H2S的气敏性质.研究结果表明,CuO纳米线阵列薄膜在250℃时对CO气体具有最强的气敏响应,并且当CO浓度增大时其气敏响应明显增强.而对于H2S气体,在常温下CuO纳米线阵列薄膜能够对低浓度的H2S气体响应,说明这种CuO纳米线阵列薄膜可以在常温、低浓度下探测H2S气体;而当测试温度升高时,其电阻值在H2S气体氛围中迅速减小.我们对这种异常的电阻变化现象进行了解释.

References

[1]  4 陈秀琴, 苏雅玲, 张兴旺, 等. 可见光响应型S, F 共掺杂TiO2 纳米管的制备. 科学通报, 2008, 53: 1274-1278
[2]  5 刘扬, 嵇天浩, 周吉, 等. 由钛酸盐纳米带水热制备锐钛矿型TiO2 纳米带. 高等学校化学学报, 2010, 31: 1297-1302
[3]  7 张斌, 周少敏, 刘兵, 等. 氧化锌纳米线阵列的制备及发光特性研究. 中国科学E 辑: 技术科学, 2009, 39: 256-260
[4]  8 Park J, Moon J, Lee S, et al. Structure and CO gas sensing properties of electrospun TiO2 nanofibers. Mater Lett, 2010, 64: 255-257??
[5]  13 Hsueh T J, Hsu C L, Chang S J, et al. Laterally grown ZnO nanowire ethanol gas sensors. Sens Actuat B, 2007, 126: 473-477??
[6]  17 Li X Z, Zhang J, Yuan Y W, et al. Effect of electric field on CuO nanoneedle growth during thermal oxidation and its growth mechanism.J Appl Phys, 2010, 108: 024308??
[7]  18 Park Y W, Seong N J, Jung H J, et al. Growth mechanism of the copper oxide nanowires from copper thin films deposited onCuO-buffered silicon substrate. J Electrochem Soc, 2010, 157: K119-K124
[8]  19 Ding J H, McAvoy T J, Cavicchi R E, et al. Surface state trapping models for SnO2-based microhotplate sensors. Sens Actuat B, 2001, 77:597-613??
[9]  20 Kim Y S, Hwang I S, KimS J, et al. CuO nanowire gas sensors for air quality control in automotive cabin. Sens Actuat B, 2008, 135:298-303??
[10]  21 Kolmakov A, Zhang Y, Cheng G, et al. Detection of CO and O2 using tin oxide nanowire sensors. Adv Mater, 2003, 15: 997-1000??
[11]  22 Chen J, Wang K, Hartman L, et al. H2S detection by vertically aligned CuO nanowire array sensors. J Phys Chem C, 2008, 112:16017-16021??
[12]  1 Comini E, Faglia G, Sberveglieri G, et al. Stable and highly sensitive gas sensors based on semiconducting oxide nanobelts. Appl PhysLett, 2002, 81: 1869-1871
[13]  2 Liao L, Lu H B, Li J C, et al. The sensitivity of gas sensor based on single ZnO nanowire modulated by helium ion radiation. Appl PhysLett, 2007, 91: 173110
[14]  3 Liao L, Zhang Z, Yan B, et al. Multifunctional CuO nanowire devices: p-type field effect transistors and CO gas sensors. Nanotechnology,2009, 20: 085203??
[15]  6 王丹丽, 阮永丰, 张灵翠, 等. ZnO 纳米线阵列的电沉积法制备及表征. 物理化学学报, 2010, 26: 3369-3372
[16]  9 郑凯波, 李静雷, 孙大林, 等. 单根ZnO 纳米线的室温气敏特性. 物理化学学报, 2008, 24: 1080-1084
[17]  10 Kolmakov A, Klenov D O, Lilach Y, et al. Enhanced gas sensing by individual SnO2 nanowires and nanobelts functionalized with Pd catalystparticles. Nano Lett, 2005, 5: 667-673??
[18]  11 Chang S J, Hsueh T J, Chen I C, et al. Highly sensitive ZnO nanowire CO sensors with the adsorption of Au nanoparticles. Nanotechnology,2008, 19: 175502??
[19]  12 Liao L, Lu H B, Shuai M, et al. A novel gas sensor based on field ionization from ZnO nanowires: Moderate working voltage and highstability. Nanotechnology, 2008, 19: 175501??
[20]  14 Jiang X C, Herricks T, Xia Y N. CuO nanowires can be synthesized by heating copper substrates in air. Nano Lett, 2002, 2: 1333-1338??
[21]  15 Cheng G, Wang S J, Cheng K, et al. The current image of a single CuO nanowire studied by conductive atomic force microscopy. ApplPhys Lett, 2008, 92: 223116??
[22]  16 Wang L X, Cheng G, Jiang X H, et al. Modulating the surface states of electric field assembled CuO nanowires by electrochemical depositionmethod. Appl Phys Lett, 2009, 95: 083107??

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133