全部 标题 作者
关键词 摘要

OALib Journal期刊
ISSN: 2333-9721
费用:99美元

查看量下载量

相关文章

更多...
化工学报  2015 

牛血清白蛋白和溶菌酶混合溶液的泡沫性能与其浓度的关系

DOI: 10.11949/j.issn.0438-1157.20150269, PP. 4107-4114

Keywords: 泡沫,稳定性,起泡性,表面张力,表面活性物质,泡沫性能

Full-Text   Cite this paper   Add to My Lib

Abstract:

生物表面活性物质的浓度对其溶液的泡沫性能有很大的影响。泡沫性能包括起泡性和泡沫稳定性。本文以初始泡沫高度和泡沫半衰期分别表征了起泡性和泡沫稳定性。首先利用Szyszkowski扩展方程和Rosen的经验模型,导出了低于临界胶束浓度(CMC)时,两种表面活性物质混合溶液的初始泡沫高度与其各自浓度的关系式;然后根据泡沫相中溶液的重力势能和表面能随气泡破裂而减小的规律,建立了低于CMC时两种表面活性物质混合溶液的泡沫半衰期与其各自浓度的关系式;最后用牛血清白蛋白(BSA)和溶菌酶(LZM)作为实验物系考察了这两种关系式的准确性。结果表明这两种关系式能准确预测BSA和LZM混合溶液的泡沫性能。在BSA和LZM混合溶液中,BSA能显著影响溶液的泡沫性能,而LZM对溶液泡沫性能的影响小。

References

[1]  Tuckermann R. Surface tension of aqueous solutions of water-soluble organic and inorganic compounds [J]. Atmospheric Environment, 2007, 41 (29): 6265-6275.
[2]  Hey M J, Kippax P G. Surface tensions of mixed aqueous solutions of tert-butanol and n-pentanol [J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2005, 262 (1/2/3): 198-203.
[3]  Anna Z. The adsorption properties of short chain alcohols and Triton X-100 mixtures at the water-air interface [J]. Journal of Colloid and Interface Science, 2009, 335 (2): 175-182.
[4]  Aumann E, Hildemann L M, Tabazadeh A. Measuring and modeling the composition and temperature-dependence of surface tension for organic solutions [J]. Atmospheric Environment, 2010, 44 (3): 329-337.
[5]  Rosen M J, Solash J. Factors affecting initial foam height in the Ross-Miles foam test [J]. Journal of the American oil Chemists' Society, 1969, 46: 399-402.
[6]  Eisner M D, Jeelani S A K, Bernhard L, Windhab E J. Stability of foams containing proteins, fat particles and nonionic surface active materials [J]. Chemical Engineering Science, 2007, 62: 1974-1987.
[7]  Alahverdjieva V S, Khristov Khr, Exerowa D, Miller R. Correlation between adsorption isotherms, thin liquid films and foam properties of protein/surface active material mixtures: Lysozyme/C10DMPO and lysozyme/SDS [J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2008, 323 (1/2/3): 132-138.
[8]  Wang Wen (王闻), Zhuang Xinshu (庄新姝), Yuan Zhenhong (袁振宏), Yu Qiang (余强), Qi Wei (亓伟), Wang Qiong (王琼), Tan Xuesong (谭雪松). Effects of ions and surface active material on enzymatic hydrolysis of sweet sorghum bagasse [J]. CIESC Journal (化工学报), 2013, 64 (10): 3767-3774.
[9]  Phillips M C. Protein conformation at liquid interfaces and its role instabilising emulsions and foams [J]. Food Technology, 1981, 35: 50-57.
[10]  Graham D E, Phillips M C. Proteins at liquid interfaces (Ⅱ): Adsorption isotherms [J]. Journal of Colloid and Interface Science, 1979, 70: 415-426.
[11]  Graham D E, Phillips M C. The Conformation of Proteins at the Airwater Interface and Their Role in Stabilising Foams [M]. New York: Academic Press, 1976: 237-255.
[12]  Burghoff B. Foam fractionation applications [J]. Journal of Biotechnology, 2012, 161: 126-137.
[13]  Wang Y, Nan F, Zheng H, Wu Z. Effects of temperature and trehalose on foam separation of nisin from the culture broth produced by Lactococcus lactis subspecies lactis W28 [J]. Journal of Dairy Science, 2012, 95: 5588-5596.
[14]  Zhang F, Wu Z L, Wu Z J, Wang H W. Effect of ionic strength on the foam separation of nisin from the fermentation broth [J]. Separation and Purification Technology, 2011, 78: 42-48.valuation of equilibrium models[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2001, 178(1-3): 1-40
[15]  Hedreul C, Frens G. Foam stability [J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2001, 186: 73.
[16]  Pandey S, Bagwe R P, Shah D O. Effect of counterions on surface and foaming properties of dodecyl sulfate [J]. Journal of Colloid and Interface Science, 2003, 267 (1): 160-166.
[17]  Langevin D. Polyelectrolyte and surface active material mixed solutions: behavior at surfaces and in thin films [J]. Advances in Colloid and Interface Science, 2001, 89/90: 467-484.
[18]  Ozdemir G, Peker S, Helvaci S S. Effect of pH on the surface and interfacial behavior of rharnnolipids R1 and R2 [J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2004, 234 (1/2/3): 135-143.
[19]  Samanta S, Ghosh P. Coalescence of bubbles and stability of foams in aqueous solutions of Tween surface active materials [J]. Chemical Engineering Research and Design, 2011, 89 (11A): 2344-2355.
[20]  Butler J A V. Chemical Thermodynamics [M]. London: Macmillan, 1962.
[21]  Hu Y F, Lee H. Prediction of the surface tension of mixed electrolyte solutions based on the equation of Patwardhan and Kumar and the fundamental Butler equations [J]. Journal of Colloid and Interface Science, 2004, 269 (2): 442-448.
[22]  Brown A K, Kaul A, Varley J. Continuous foaming for protein recovery (Part Ⅱ): Selective recovery of proteins from binary mixtures [J]. Biotechnology and Bioengineering, 1999, 62 (3): 291-300.
[23]  Hernáinz F, Caro A. Variation of surface tension in aqueous solutions of sodium dodecyl sulfate in the flotation bath [J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2002, 196 (1): 19-24.
[24]  Lee J Y, Hildemann L M. Surface tension of solutions containing dicarboxylic acids with ammonium sulfate, D-glucose, or humic acid [J]. Journal of Aerosol Science, 2013, 64: 94-102.
[25]  Prosser A J, Franses E I. Adsorption and surface tension of ionic surface active materials at the air-water interface: review and evaluation of equilibrium models [J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2001, 178 (1/2/3): 1-40.
[26]  Tuckermann R. Surface tension of aqueous solutions of water-soluble organic and inorganic compounds[J]. Atmospheric Environment, 2007, 41(29): 6265-6275
[27]  Hey M J, Kippax P G. Surface tensions of mixed aqueous solutions of tert-butanol and n-pentanol[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2005, 262(1-3): 198-203
[28]  Anna Z. The adsorption properties of short chain alcohols and Triton X-100 mixtures at the water-air interface[J]. Journal of Colloid and Interface Science, 2009, 335(2): 175-182
[29]  Aumann E, Hildemann L M, Tabazadeh A. Measuring and modeling the composition and temperature-dependence of surface tension for organic solutions[J]. Atmospheric Environment, 2010, 44(3): 329-337
[30]  Rosen M J, Solash J. Factors affecting initial foam height in the Ross-Miles foam test[J]. Journal of the American oil Chemists’ Society, 1969, 46: 399-402
[31]  Eisner M D, Jeelani S A K, Bernhard L, Windhab E J. Stability of foams containing proteins, fat particles and nonionic surface active materials[J]. Chemical Engineering Science, 2007, 62: 1974-1987
[32]  Alahverdjieva V S, Khristov Khr, Exerowa D, Miller R. Correlation between adsorption isotherms, thin liquid films and foam properties of protein/surface active material mixtures: Lysozyme/C10DMPO and lysozyme/SDS[J]. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2008, 323(1-3): 132-138
[33]  Wang Wen(王闻), Zhuang Xinshu(庄新姝), Yuan Zhenhong(袁振宏), Yu Qiang(余强), Qi Wei(亓伟), Wang Qiong(王琼), Tan Xuesong(谭雪松). Effects of ions and surface active material on enzymatic hydrolysis of sweet sorghum bagasse[J]. CIESC Journal(化工学报), 2013, 64(10): 3767-3774
[34]  Phillips M C. Protein conformation at liquid interfaces and its role instabilising emulsions and foams[J]. Food Technology, 1981, 35: 50-57
[35]  Graham D E, Phillips M C. Proteins at liquid interfaces. II. Adsorption isotherms[J]. Journal of Colloid and Interface Science, 1979, 70: 415-426
[36]  Graham D E, Phillips M C. The conformation of proteins at the airwater interface and their role in stabilising foams[M]. New York: Academic Press, 1976: 237-255
[37]  Burghoff B. Foam fractionation applications[J]. Journal of Biotechnology,2012, 161: 126-137
[38]  Wang Y, Nan F, Zheng H, Wu Z. Effects of temperature and trehalose on foam separation of nisin from the culture broth produced by Lactococcus lactis subspecies lactis W28[J]. Journal of Dairy Science, 2012, 95: 5588-5596
[39]  Zhang F, Wu Z L, Wu Z J, Wang H W. Effect of ionic strength on the foam separation of nisin from the fermentation broth[J]. Separation and Purification Technology, 2011, 78: 42-48 ?

Full-Text

Contact Us

service@oalib.com

QQ:3279437679

WhatsApp +8615387084133