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化工学报  2014 

亚乙基降冰片烯的合成

DOI: 10.3969/j.issn.0438-1157.2014.01.004, PP. 32-38

Keywords: 亚乙基降冰片烯,反应,异构化反应,丁二烯,(双)环戊二烯,合成,聚合

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Abstract:

近年来,随着三元乙丙橡胶的广泛应用,作为其首选第三单体的亚乙基降冰片烯(ENB)越来越受到关注。综述了ENB的反应机理、合成工艺、生产情况及市场动向。在反应机理方面主要包括先由双环戊二烯在高温下裂解成的环戊二烯与丁二烯经Diels-Alder反应生成中间体乙烯基降冰片烯(VNB),再经其异构化反应制得亚乙基降冰片烯。重点阐述了乙烯基降冰片烯合成阶段副反应控制的工艺优化,以及VNB异构化阶段不同类型催化剂的影响等。

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