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化工学报  2014 

甘蔗渣在高温液态水中的超微结构与组分变化

DOI: 10.3969/j.issn.0438-1157.2014.12.049, PP. 5010-5016

Keywords: 高温液态水,生物质,显微结构,化学分析

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Abstract:

木质纤维素类物质中天然纤维素与半纤维素、木质素等组分交联形成了坚固的细胞壁,对纤维素酶水解和微生物消化表现出一定的抗性,原料预处理可以克服细胞壁抗性,提高木质纤维多糖生化转化效率.从细胞壁超微结构层次入手,对甘蔗渣细胞壁在高温液态水预处理过程中的解构机理进行了深入研究.未处理甘蔗渣细胞壁分层现象明显,由外至内分别为胞间层(ML)、初生壁(P)及次生壁(S),高温液态水预处理后各层界线变得模糊.SEM-EDXA分析表明细胞壁各层木质素分布发生了迁移,水解液中的木聚糖和木质素衍生物在细胞壁表面凝集生成类木质素滴状沉淀物.拉曼光谱分析结果显示预处理后纤维素在细胞壁各层分布趋于均质化.

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