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化工学报  2013 

二氧化碳置换法模拟开采天然气水合物的研究进展

DOI: 10.3969/j.issn.0438-1157.2013.07.001, PP. 2309-2315

Keywords: 天然气水合物,置换,甲烷,二氧化碳,模拟开采

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Abstract:

目前实验室模拟开采天然气水合物(NGH)的最主要的方法为外激法,通过注热、降压等方式使水合物分解释放出甲烷(CH4),外激法最大的问题在于水合物的分解容易造成地层结构变化,导致地质斜坡灾害。利用二氧化碳(CO2)在水合物相中置换开采CH4,由于置换过程发生在水合物相中,不改变水合物相结构,因此可以降低地质灾害风险。本文全面介绍了利用CO2在水合物相从NGH中置换CH4的研究进展,从置换可行性、动力学模型、模拟研究、实验研究等方面对当前的研究进行了综述,并为进一步发展置换法开采CH4技术指出了方向。

References

[1]  Davy H.On some of the combinations of oxymuriatic gas and oxygene and on the chemical relations of these principles to inflammable bodies[J].Philosophical Transactions of the Royal Society (London),1810,101:35
[2]  Hammerschmidt E G.Formation of gas hydrates in natural gas transmission lines[J].Ind.Eng.Chem.,1934,26:851-855
[3]  Sloan E D.Clathrate hydrates of natural gases//Koh C A.Chemical Industrial Series:119[M].3rd ed.Golden,Colorado,U.S.A:CRC Press,2008:721
[4]  Boswell R,Kleinberg R,Collett T,Frye M.Exploration priorities for marine gas hydrates.Fire in the ice (The National Energy Technology Laboratory Methane Hydrate Newsletter)[R].2007
[5]  Tang L G,Xiao R,Huang C,Feng Z P,Fan S S. Experimental investigation of production behavior of gas hydrate under thermal stimulation in unconsolidated sediment[J].Energ.Fuel,2005,19 (6):2402-2407
[6]  Li X S,Wan L H,Li G,Li Q P,Chen Z Y,Yan K F. Experimental investigation into the production behavior of methane hydrate in porous sediment with hot brine stimulation[J].Ind.Eng.Chem.Res.,2008,47 (23):9696-9702
[7]  Tang L G,Li X S,Feng Z P,Li G,Fan S S.Control mechanisms for gas hydrate production by depressurization in different scale hydrate reservoirs[J].Energ.Fuel,2007,21 (1):227-233
[8]  Sun X,Nanchary N,Mohanty K K.1-D modeling of hydrate depressurization in porous media[J].Transport Porous Med.,2005,58 (3):315-338
[9]  Li G,Li X S,Wang Y,Zhang Y.Production behavior of methane hydrate in porous media using huff and puff method in a novel three-dimensional simulator[J].Energy,2011,36 (5):3170-3178
[10]  Li G,Moridis G J,Zhang K N,Li X S.Evaluation of gas production potential from marine gas hydrate deposits in Shenhu area of South China Sea[J].Energ.Fuel,2010,24:6018-6033
[11]  Yuan Q,Sun C Y,Yang X,Ma P C,Ma Z W,Liu B,et al. Recovery of methane from hydrate reservoir with gaseous carbon dioxide using a three-dimensional middle-size reactor[J].Energy,2012,40 (1):47-58
[12]  White M,McGrail P.Designing a pilot-scale experiment for the production of natural gas hydrates and sequestration of CO2 in class 1 hydrate accumulations[J].Greenhouse Gas Control Technologies,2009,1 (1):3099-3106
[13]  Sum A K,Burruss R C,Sloan E D.Measurement of clathrate hydrates via Raman spectroscopy[J].J. Phys. Chem.B,1997,101 (38):7371-7377
[14]  Koh D Y,Kang H,Kim D O,Park J,Cha M,Lee H.Recovery of methane from gas hydrates intercalated within natural sediments using CO2 and a CO2/N2 gas mixture[J].Chemsuschem,2012,5 (8):1443-1448
[15]  Liu Fangfang(刘芳芳),Liu Xiaodong(刘晓栋).New technologies for producing natural gas hydrate and constraints for industrial application[J].Special Oil and Gas Reservoirs (特种油罐气),2010,17 (3):1-4
[16]  Yan Kefeng(颜克凤),Li Xiaosen(李小森),Chen Zhaoyang(陈朝阳),Li Gang(李刚),Zhang Yu(张郁).Research on replacement exploitation of natural gas hydrate with carbon dioxide[J].Modern Chemical Industry(现代化工),2012,32 (8):42-49
[17]  Kvenvolden K A.Gas hydrates-geological perspective and global change[J].Rev.Geophys.,1993,31 (2):173-187
[18]  Folger P.Gas hydrate:resource and hazard//CRS Report for Congress.2010:9
[19]  Graue A,Kvamme B,Baldwin B A,Stevens J,Howard J,Aspenes E,et al.Environmentally friendly CO2 storage in hydrate reservoirs benefits from associated spontaneous methane production//Offshore Technology Conference.Houston,Texas,2006
[20]  Ohgaki K,Takano K,Sangawa H,Matsubara T,Nakano S.Methane exploitation by carbon dioxide from gas hydrates-phase equilibria for CO2-CH4 mixed hydrate system[J].J.Chem.Eng.Jpn.,1996,29 (3):478-483
[21]  Hirohama S,Shimoyama Y,Wakabayashi A,Tatsuta S,Nishida N.Conversion of CH4-hydrate to CO2-hydrate in liquid CO2[J].J.Chem.Eng.Jpn.,1996,29 (6):1014-1020
[22]  Komai T,Yamamoto Y.Equilibrium properties and kinetics of methane and carbon dioxide gas hydrate formation/dissociation[J].Abstr.Pap.Am.Chem.S,1997,213:90-Fuel
[23]  Nakano S,Yamamoto K,Ohgaki K.Natural gas exploitation by carbon dioxide from gas hydrate fields-high-pressure phase equilibrium for an ethane hydrate system[J].P I Mech.Eng.a-J.Pow.,1998,212 (A3):159-163
[24]  Smith D H,Seshadri K,Wilder J W.Assessing the thermodynamic feasibility of the conversion of methane hydrate into carbon dioxide hydrate in porous media//Proceedings of First National Conference on Carbon Sequestration[C].National Energy Technology Laboratory,2001
[25]  Zhao J F,Xu K,Song Y C,Liu W G,Lam W,Liu Y,et al.A review on research on replacement of CH4 in natural gas hydrates by use of CO2[J].Energies,2012,5 (2):399-419
[26]  Zhou X T,Fan S S,Liang D Q,Du J W.Determination of appropriate condition on replacing methane from hydrate with carbon dioxide[J].Energ.Convers.Manage.,2008,49 (8):2124-2129
[27]  Uchida T,Ikeda I Y,Takeya S,Kamata Y,Ohmura R,Nagao J,et al.Kinetics and stability of CH4-CO2 mixed gas hydrates during formation and long-term storage[J].Chemphyschem,2005,6 (4):646-654
[28]  Anderson R,Llamedo M,Tohidi B,Burgass R W.Experimental measurement of methane and carbon dioxide clathrate hydrate equilibria in mesoporous silica[J].J.Phys.Chem.B,2003,107 (15):3507-3514
[29]  Ota M,Abe Y,Watanabe M,Smith R L,Inomata H. Methane recovery from methane hydrate using pressurized CO2[J].Fluid Phase Equilibr.,2005,228:553-559
[30]  Yan Kefeng (颜克凤),Li Xiaosen(李小森),Chen Zhaoyang (陈朝阳),Xu Chungang (徐纯刚).Molecular dynamics simulation of CO2 separation from integrated gasification combined cycle syngas via the hydrate formation[J].Acta Phys. Sin.-Ch. Ed. (物理学报),2010,59 (6):4313-4321
[31]  Yan Kefeng (颜克凤),Li Xiaosen(李小森),Chen Zhaoyang (陈朝阳),Li Gang (李刚),Li Zhibao (李志宝).Molecular dynamics simulation of methane hydrate dissociation by thermal stimulation in conjunction with chemical injection method[J].Acta Phys. Sin.-Ch. Ed. (物理学报),2007,56 (11):6727-6735
[32]  Yezdimer E M,Cummings P T,Chialvo A A. Determination of the Gibbs free energy of gas replacement in sⅠ clathrate hydrates by molecular simulation[J].J.Phys.Chem.A,2002,106(34):7982-7987
[33]  Geng C Y,Wen H,Zhou H.Molecular simulation of the potential of methane reoccupation during the replacement of methane hydrate by CO2[J].J.Phys.Chem.A,2009,113 (18):5463-5469
[34]  Uchida T,Takeya S,Ebinuma T.Replacing methane with CO2 in clathrate hydrate:observation using Raman spectroscopy//Proceedings of the 5th International Conference on Greenhouse Gas Control Technologies[C].Cairns,Australia,2000
[35]  Ota M,Morohashi K,Abe Y,Watanabe M,Smith R L,Inomata H.Replacement of CH4 in the hydrate by use of liquid CO2[J].Energ.Convers.Manage.,2005,46 (11/12):1680-1691
[36]  Vanderwaals J H,Platteeuw J C.Clathrate solutions[J].Adv.Chem.Phys.,1959,2:1-57
[37]  Soave G.Equilibrium constants from a modified Redlich-Kwong equation of state[J].Chem.Eng.Sci.,1972,27 (6):1197-1203
[38]  Kvamme B,Graue A,Aspenes E,Kuznetsova T,Granasy L,Toth G,et al.Kinetics of solid hydrate formation by carbon dioxide:phase field theory of hydrate nucleation and magnetic resonance imaging[J].Phys. Chem. Chem.Phys.,2004,6 (9):2327-2334
[39]  Kvamme B,Graue A,Buanes T,Kumetsoua T,Ersland G.Storage of CO2 in natural gas hydrate reservoirs and the effect of hydrate as an extra sealing in cold aquifers[J].Int.J.Greenh.Gas Con.,2007,1 (2):236-246
[40]  Yoon J H,Kawamura T,Yamamoto Y,Komai T. Transformation of methane hydrate to carbon dioxide hydrate:in situ Raman spectroscopic observations[J].J.Phys.Chem.A,2004,108 (23):5057-5059
[41]  Tegze G,Pusztai T,Toth G,Granasy L,Svandal A,Buanes T,et al.Multiscale approach to CO2 hydrate formation in aqueous solution:phase field theory and molecular dynamics.Nucleation and growth[J].J. Chem. Phys.,2006,124 (23):234710
[42]  Iwai Y,Nakamura H,Hirata M.Molecular dynamics simulation of replacement of methane hydrate with carbon dioxide[J].Mol.Simulat.,2012,38 (6):481-490
[43]  Bai D S,Zhang X R,Chen G J,Wang W C.Replacement mechanism of methane hydrate with carbon dioxide from microsecond molecular dynamics simulations[J].Energ.Environ.Sci.,2012,5 (5):7033-7041
[44]  Tung Y T,Chen L J,Chen Y P,Lin S T.In situ methane recovery and carbon dioxide sequestration in methane hydrates:a molecular dynamics simulation study[J].J.Phys.Chem.B,2011,115 (51):15295-15302
[45]  Wang Jinbao (王金宝),Guo Xuqiang (郭绪强),Chen Guangjin (陈光进),Li Zunzhao (李遵照),Yang Lanying (杨兰英).Experimental research on methane recovery from natural gas hydrates by carbon dioxide replacement[J].J.Chem.Eng.Chin.Univ.(高校化学工程学报),2007,21:715-719
[46]  Lee H,Seo Y,Seo Y T,Moudrakovski I L,Ripmeester J A.Recovering methane from solid methane hydrate with carbon dioxide[J].Angew.Chem.Int.Edit,2003,42 (41):5048-5051
[47]  Xiong L J,Li X S,Zeng Z Y,Li G,Chen Z Y,Zhang Y,et al.Experimental investigation into replacement of CH4 in hydrate in porous sediment with liquid CO2 injection// Proceedings of the 7th International Conference on Gas Hydrate (ICGH)[C].Edinburgh,UK,2011
[48]  Yuan Q,Sun C Y,Liu B,Wang X,Ma Z W,Ma Q L,et al.Methane recovery from natural gas hydrate in porous sediment using pressurized liquid CO2[J].Energ. Convers. Manage.,2013,67:257-284
[49]  Zhou X T,Fan S S,Liang D Q,Du J W.Replacement of methane from quartz sand-bearing hydrate with carbon dioxide-in-water emulsion[J].Energ.Fuel,2008,22 (3):1759-1764
[50]  Zhang Wei (张伟),Wang Zhao(王赵),Li Wenqiang (李文强),Li Wenyong (李文雍),He Dewei (贺德威).Research progress in enhanced replacing methane out of gas hydrate by carbon dioxide emulsion[J].Nat.Gas Chem. Eng.(天然气化工),2009,34:5
[51]  McGrail B P,Zhu T,Hunter R B,White M D,Patil S L,Kulkarni A S.A new method ofr enhanced production of gas hydrate with CO2//Proceedings of the AAPG Hedberg Conference on Gas Hydrates:Energy Resource Potential and Associated Geologic Hazards[C].Vancouver,Canada,2004

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