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化工学报  2014 

添加剂对NOxOUT脱硝及N2O、CO生成的影响特性

DOI: 10.3969/j.issn.0438-1157.2014.06.038, PP. 2232-2240

Keywords: 污染,NOxOUT,脱除特点,温室气体,N2O,添加剂,动力学,生成规律

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Abstract:

通过试验研究了NOx污染的NOxOUT脱除特点和温室气体N2O及CO的生成规律,结合动力学分析,探讨了添加剂的作用。结果表明:在不同氨氮比(NSR)下,最佳反应温度为950℃,最高脱硝效率可达76.33%;N2O随温度的生成曲线类似于效率曲线,在950℃左右达到最大排放量;N2O的排放随NSR和氧量的增加而升高;温度较高时,N2O的排放随停留时间的延长先增加后减少;碳酸钠、乙酸钠、谷氨酸钠及乙醇可有效提高低温侧的脱硝效率和拓宽相应的温度窗口,其中谷氨酸钠最为明显;脱硝效率随钠盐添加量的变化与温度有关,钠原子最佳添加量为60ml·L-1;上述添加剂均可明显降低中高温段的N2O、CO排放,低温端则相反;N2O、CO的排放随温度、添加剂种类及浓度的不同而呈现各自的变化趋势。

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