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化工学报  2015 

可逆气态膜-多效膜蒸馏-精馏过程脱除水相氨氮副产氨水

DOI: 10.11949/j.issn.0438-1157.20150901, PP. 3588-3596

Keywords: 可逆气态膜,多效膜蒸馏,,蒸馏,,吸收,再生,节能

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Abstract:

可逆气态膜-多效膜蒸馏-精馏耦合工艺可用于脱除料液或废水中的氨氮并得到高纯浓氨水。考察了磷酸二氢铵为可逆吸收剂时气态膜法脱氨效果和多效膜蒸馏-精馏法吸收完成液再生效果。实验结果表明:可逆气态膜总传质系数K和单程氨氮脱除率η分别可达13.9μm·s-1和97.5%,废水氨氮值可降至5mg·L-1以下;吸收完成液经多效膜蒸馏预浓缩后再经精馏再生可同时得到浓度为5%~18%的氨水。该耦合过程电耗极小的同时蒸汽耗量为28~40kg·m-3废水,约为单纯精馏过程的1/5。此外气态膜脱氨和多效膜蒸馏预浓缩过程有效地阻止了废水中挥发性杂质进入浓氨水产品。该过程对气态膜和膜蒸馏用微孔疏水膜组件的稳定性要求苛刻,长期操作试验显示聚四氟乙烯膜能够满足此要求。

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