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化工学报  2015 

甲基丙烯酸接枝改性玉米芯对Cd2+的吸附及机理

DOI: 10.11949/j.issn.0438-1157.20150507, PP. 4509-4519

Keywords: 甲基丙烯酸,接枝改性,玉米芯,吸附,制备,Cd2+,动力学,zeta电位

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Abstract:

以甲基丙烯酸为单体、高锰酸钾/浓硫酸为引发体系对玉米芯进行接枝改性,成功引入羧基官能团,结合扫描电镜、红外光谱和zeta电位等分析手段研究了吸附条件对玉米芯吸附Cd2+过程的影响及其吸附机理。结果表明,吸附过程符合Langmuir模型和准二级动力学方程,改性玉米芯对Cd2+的吸附主要是化学吸附过程,吸附速率是颗粒内扩散速率和膜扩散速率共同影响的结果;在pH7、投加量为5g·L-1、温度为30℃、吸附时间为6h的条件下,接枝改性玉米芯和原玉米芯对Cd2+的最大吸附容量分别为28.00mg·g-1和5.96mg·g-1,提高了近4倍;玉米芯对Cd2+的吸附是一个自发的吸热反应,温度越高,自发程度越大;接枝改性玉米芯对Cd2+的吸附过程中,参与反应的主要官能团有羧基、羟基、酰胺基和甲基等,吸附Cd2+后的接枝改性玉米芯表面出现褶皱和白色小颗粒,孔隙消失,电负性增大。

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