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化工学报  2015 

可溶性近红外吸收剂氨基酞菁的合成及应用

DOI: 10.11949/j.issn.0438-1157.20141576, PP. 1577-1584

Keywords: 氨基酞菁,溶解性,吸收,近红外吸收涂层,酞菁,

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Abstract:

通过先合成脂肪氨基邻苯二腈再合成酞菁的工艺制备了一系列可溶性近红外吸收氨基酞菁。采用核磁共振氢谱(1HNMR)、红外光谱(FT-IR)、溶解性实验、紫外吸收光谱(UV-Vis)、热重分析法(TGA)对氨基酞菁的结构和性能进行了表征。结果表明成功合成了不同结构的氨基酞菁。在酞菁外围a位取代脂肪族氨基以及采用Mn2+配位,可以得到较高溶解性的氨基酞菁。脂肪族氨基的供电子性能,尤其是a位取代,配合Mn2+,可使酞菁Q带出现较大红移,3,3',3",3"'-四正丁氨基锰酞菁(a-TnBAMnPc)在三氯甲烷溶液中的最大吸收波长可达870nm。研究了a-TnBAMnPc在聚甲基丙烯酸甲酯(PMMA)和水性聚氨酯(WPU)中的近红外吸收性能,在PMMA膜片中,a-TnBAMnPc的添加量超过0.60%(质量分数)时,在862nm波长处透过率为0;在WPU涂层中,a-TnBAMnPc含量超过0.40%(质量分数)时,在866nm波长处透过率为0。

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